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Graft copolymerization of styrene onto cellulose acetate p-nitrobenzoate by chain transfer reaction
Authors:Shigeo Nakamura  Eimei Yoshikawa  Kei Matsuzaki
Abstract:Styrene was grafted onto cellulose acetate p-nitrobenzoate (CANB) by chain transfer reaction of growing polymer radicals to the pendant nitro groups of CANB. A copolymer with a branch for every 17.2 nitro groups was obtained. This result indicates that the pendant aromatic nitro group is more effective in obtaining a graft copolymer by radical mechanism than pendant double bond on the trunk polymer previously reported, where graft copolymers with a branch for several hundred of double bonds are produced.
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