Polymerization of lactams, 38. Copolymerization of 6-caprolactam with some of its non-homopolymerizing derivatives |
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Authors: | Jaroslava Kondelí kov ,Jan ejba,Jaroslav Kr lí
ek,Zdena Smr
kov |
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Affiliation: | Jaroslava Kondelíková,Jan Šejba,Jaroslav Králíček,Zdena Smrčková |
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Abstract: | It was demonstrated that non-homopolymerizing derivatives of 6-caprolactam: 7-cyclohexyl-1-aza-2-cycloheptanone (I) and 7-isopropyl-5-methyl-1-aza-2-cycloheptanone (II) were polymerizing with 6-caprolactam under conditions of the socalled hydrolytic polymerization. With its increasing content in the initial reaction mixture the copolymerization rate, the equilibrium content of the copolymer, and the reduced viscosity decreased. Lactam (I) was a more reactive comonomer in comparison with lactam (II). |
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