| 3－乙酰氧基－1，3，5（10），15－雌四烯－17－酮与甘氨酸甲酯Michael加成反应的研究 |
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| 引用本文： | 薛凤兰,田树盛.3－乙酰氧基－1，3，5（10），15－雌四烯－17－酮与甘氨酸甲酯Michael加成反应的研究[J].北京服装学院学报,1996(1). |
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| 作者姓名： | 薛凤兰 田树盛 |
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| 作者单位： | 北京服装学院精细化工系 |
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| 摘 要： | 以３－乙酰氧基－１，３，５（１０），１５－雌四烯－１７－酮和甘氨酸甲酯为原料，筛选出适宜的催化剂三乙胺和溶剂四氢呋喃，通过Ｍｉｃｈａｅｌ加成反应合成了３－乙酰氧基－１５－（Ｎ－甲氧羰亚甲基氨基）－１，３，５（１０）－雌三烯－１７－酮，并通过红外和质谱方法确定其结构．
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| 关 键 词： | Michael加成反应 3－乙酰氧基－15－（N－甲氧羰亚甲基氨基）－1，3，5（10）－雌三烯－17－酮 雌四烯 |
Study on Michael Addition of 3-Hydroxyestra-1,3,5(10),15-tetraen-17-one Acetate and Glycinemethylester |
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| Xue Fenglan,Tian Shusheng.Study on Michael Addition of 3-Hydroxyestra-1,3,5(10),15-tetraen-17-one Acetate and Glycinemethylester[J].Journal of Beijing Institute of Clothing Technology(Nature Science Edition),1996(1). |
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| Authors: | Xue Fenglan Tian Shusheng |
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| Abstract: | ydroxyestra-15-(N -methyoxycarbonylmathyleneamino)-1,3,5(10)-trien-17-one acetate was synthesized from 3-hydroxyestra-1,3,5(10),15-tetraen-17-one acetate and glycinemethylester by Michael addition reaction.Triethylamine was selected as catalyst and tetrahydrofuran as solvent.The Structure of the product was identified by IR and MS. |
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| Keywords: | Michael addition 3-hydroxyestra-15-(N-methyoxycarbonylmethyleneamino)-1 3 5(10 )-trien- 17-one acetate estratetraene |
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