| 分子筛催化合成十三碳二元酸二异辛酯的研究 |
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| 引用本文： | 刘明灯,赵文军,宋永波,高林.分子筛催化合成十三碳二元酸二异辛酯的研究[J].应用化工,2006,35(7):529-531,534. |
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| 作者姓名： | 刘明灯 赵文军 宋永波 高林 |
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| 作者单位： | 1. 中国科学院,新疆理化技术研究所,新疆,乌鲁木齐,830011;中国科学院,研究生院,北京,100049
2. 中国科学院,新疆理化技术研究所,新疆,乌鲁木齐,830011 |
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| 摘 要： | 以3、ZSM-5、HZSM-5等分子筛为催化剂,考察了十三碳二元酸与异辛醇进行酯化的反应条件。结果表明,HZSM-5分子筛在常压、温度为469 K、酸醇摩尔比为1∶4、时间为4 h、催化剂用量为2.8%,十三碳二元酸的酯化率达99%以上,产物的最后收率达84%以上,催化剂重复使用5次以上,产率没有发生明显的变化。
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| 关 键 词： | 十三碳二元酸 分子筛 异辛醇 酯化 |
| 文章编号： | 1671-3206（2006）07-0529-03 |
| 收稿时间： | 2006-04-15 |
| 修稿时间： | 2006-04-15 |
Study on synthesis of tridecane dicarboxylic acid di-2-ethylhexyl ester over zeolites |
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| LIU Ming-deng,ZHAO Wen-jun,SONG Yong-bo,GAO Lin.Study on synthesis of tridecane dicarboxylic acid di-2-ethylhexyl ester over zeolites[J].Applied chemical industry,2006,35(7):529-531,534. |
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| Authors: | LIU Ming-deng ZHAO Wen-jun SONG Yong-bo GAO Lin |
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| Affiliation: | 1. Xinjiang Technical Institute of Physics and Chemistry of Chinese Academy of Science, Ummqi 830011, China; 2. The Graduate School of Chinese Academy of Science, Beijing 100049, China |
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| Abstract: | The influence factors of esterification of isooctyl alcohol with tridecane dicarboxylic acid over zeolites 3,ZSM-5,HZSM-5 were investigated.The result showed that the appropriate condition should be:the catalyst was HZSM-5;the reaction temperature was 469 k;mole ratio of alcohol to tridecane dicarboxylic acid was 4∶1;the amount of catalyst was about 2.8% of the mass of tridecane dicarboxylic acid and the reaction time was 4 h.The esterification yield of tridecane dicarboxylic acid was 99% and the yield of ester was about 84%.The catalyst was reused five times after removing water and the yields of ester has no significant reducing. |
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| Keywords: | tridecane dicarboxylic acid zeolites isooctyl alcohol esterification |
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