| 四氨基镍酞菁在金电极上成膜过程的研究 |
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| 引用本文： | 任春生,夏静芬,邓杏娣,应敏.四氨基镍酞菁在金电极上成膜过程的研究[J].工业催化,2004,12(3):43-49. |
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| 作者姓名： | 任春生 夏静芬 邓杏娣 应敏 |
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| 作者单位： | 东华理工学院应用化学系,江西,抚州,344000;浙江万里学院,浙江,宁波,315100;东华理工学院应用化学系,江西,抚州,344000;浙江万里学院,浙江,宁波,315100 |
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| 基金项目： | 宁波市重点博士基金资助项目 (0 2J2 0 1 0 1 1 8) |
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| 摘 要： | 采用循环伏安法（CV）和石英晶体微天平技术（QCM）对四氨基镍酞菁（NiTAPc）在金电极上的聚合成膜过程进行了研究，讨论了扫描速率、溶剂、支持电解质及单体浓度对其成膜过程的影响，考察了该聚合膜在无单体电解质溶液中的氧化还原行为及稳定性。借助电化学石英晶体微天平(QCM)重点讨论了过程溶液中离子在膜中传输的机理。
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| 关 键 词： | 石英晶体微天平(EQCM) 循环伏安法 四氨基镍酞菁 成膜过程 离子传输 电催化 |
| 文章编号： | 1008-1143(2004)03-0043-07 |
| 修稿时间： | 2003年12月16 |
A study on the growth of NiTAPc on gold electrode |
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| REN Chun-sheng,XIA Jing-fen,DENG Xing-di,YING Min.A study on the growth of NiTAPc on gold electrode[J].Industrial Catalysis,2004,12(3):43-49. |
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| Authors: | REN Chun-sheng XIA Jing-fen DENG Xing-di YING Min |
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| Affiliation: | 1. Department of Applied Chemistry, East China Institute of Technology, Jiangxi Fuzhou 344000,; China; 2. Zhejiang Wanli University , Zhejiang Ningbo 315100, China |
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| Abstract: | The electropolymerization of nickel tetraaminophthalocyanine(NiTAPc) on gold electrode was studied by cyclic voltammetry and electrochemical quartz crystal microbalance(EQCM). The effects of various parameters on the polymer growth, such as solvents, electrolytes, scanning rates, and NiTAPc concentration, were investigated. The redox behaviours and stability of the conducting film in repeated charging and discharging were investigated in 0.1 mol/L TBAP solution in DMF. The mechanism for transfer of ions in the solution through the film during the process was discussed using EQCM. |
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| Keywords: | electrochemical quartz crystal microbalance(EQCM) cyclic voltammetry nickel tetraaminophthalocyanine electropolymerization ion transfer electrocatalysis |
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