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镀锌层无铬钝化工艺的研究
引用本文:郑环宇,安茂忠,赖勤志.镀锌层无铬钝化工艺的研究[J].材料保护,2005,38(9):18-21.
作者姓名:郑环宇  安茂忠  赖勤志
作者单位:哈尔滨工业大学应用化学系,黑龙江,哈尔滨,150001
摘    要:研究了用于锌镀层彩色钝化的无铬钝化液最佳配方及工艺.以钼酸盐为主要原料,通过加入协同缓蚀剂,控制工艺条件可得到呈亮丽彩虹色的钝化膜,并开发了一种封闭处理工艺以提高膜层的耐蚀性.通过电化学测试手段比较了铬酸盐钝化膜、钼酸盐钝化膜及镀锌层的耐蚀性能.

关 键 词:无铬钝化  钼酸盐  锌镀层  耐蚀性
文章编号:1001-1560(2005)09-0018-04
收稿时间:2005-04-28
修稿时间:2005-04-28

Chromium-Free Passivation Process for Zinc Coating
ZHENG Huan-yu,AN Mao-zhong,LAI Qin-zhi.Chromium-Free Passivation Process for Zinc Coating[J].Journal of Materials Protection,2005,38(9):18-21.
Authors:ZHENG Huan-yu  AN Mao-zhong  LAI Qin-zhi
Abstract:A chromium-free colorful passivation technology for zinc coating was developed. Thus the beautiful rainbow-color-like passivation film was obtained on the zinc coating by properly controlling the passivation condition in the presence of major raw material molybdate and a synergistic inhibitor. The optimized passivation process was established, and the corrosion resistance of the molybdate conversion coating was investigated by means of electrochemical techniques using chromate conversion coating and zinc coating as the comparisons. It was found that the chromium-free passivation process based on the molybdate could be used to effectively increase the corrosion resistance of the zinc coating.
Keywords:chromium-free passivation  molybdate  zinc coating  corrosion resistance
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