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Functional Properties of Plasticized Bio-Based Poly(Lactic Acid)_Poly(Hydroxybutyrate) (PLA_PHB) Films for Active Food Packaging
Authors:Nuria Burgos  Ilaria Armentano  Elena Fortunati  Franco Dominici  Francesca Luzi  Stefano Fiori  Francesco Cristofaro  Livia Visai  Alfonso Jiménez  José M. Kenny
Affiliation:1.Department of Analytical Chemistry, Nutrition and Food Sciences,University of Alicante,San Vicente del Raspeig,Spain;2.Department of Ecological and Biological Sciences (DEB),Tuscia University,Viterbo,Italy;3.Civil and Environmental Engineering Department, UdR INSTM,University of Perugia,Terni,Italy;4.Condensia Química,Barcelona,Spain;5.Molecular Medicine Department (DMM), Center for Health Technologies (CHT), UdR INSTM,University of Pavia,Pavia,Italy;6.Department of Occupational Medicine, Toxicology and Environmental Risks, Instituti Clinici Scientifici Maugeri S.p.A, IRCCS,Pavia,Italy
Abstract:Fully bio-based and biodegradable active films based on poly(lactic acid) (PLA) blended with poly(3-hydroxybutyrate) (PHB) and incorporating lactic acid oligomers (OLA) as plasticizers and carvacrol as active agent were extruded and fully characterized in their functional properties for antimicrobial active packaging. PLA_PHB films showed good barrier to water vapor, while the resistance to oxygen diffusion decreased with the addition of OLA and carvacrol. Their overall migration in aqueous food simulant was determined and no significant changes were observed by the addition of carvacrol and OLA to the PLA_PHB formulations. However, the effect of both additives in fatty food simulant can be considered a positive feature for the potential protection of foodstuff with high fat content. Moreover, the antioxidant and antimicrobial activities of the proposed formulations increased by the presence of carvacrol, with enhanced activity against Staphylococcus aureus if compared to Escherichia coli at short and long incubation times. These results underlined the specific antimicrobial properties of these bio-films suggesting their applicability in active food packaging.
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