Synthesis and gas permeability of membranes of Poly(vinyl ether)s bearing oxyethylene segments

Cationic copolymerizations of vinyl ether monomers [2-methoxyethyl vinyl ether: MOVE, 2-(2-methoxyethoxy)ethyl vinyl ether: MEEVE, 2-adamantyl vinyl ether: AdVE, 2-(2-vinyloxyethoxy)ethyl methacrylate: VEEM] were performed to obtain three types of vinyl ether copolymers [poly(MOVE-AdVE)s, poly(MEEVE-AdVE)s, and poly(MEEVE-VEEM)s] with different composition rates. Poly(MOVE-AdVE) and poly(MEEVE-AdVE) obtained at monomer feed ratio of 1:1 exhibited the glass transition temperatures (T_g) of 55 and 28 °C, respectively, but the T_g's of copolymers were near or lower than room temperature when the feed ratio of AdVE decreased. Poly(MOVE-AdVE)s and poly(MEEVE-AdVE) with T_g's above room temperature afforded free-standing membranes by casting them from toluene solutions. They exhibited relatively high CO₂ permeability and high CO₂/N₂ separation factors (P(CO₂) = 22–36 barrers, P(CO₂)/P(N₂) = 19–40). The T_g's of poly(MEEVE-VEEM)s were very low and around ?70 °C irrespective of the difference of monomer feed ratio. Methacrylate groups in poly(MEEVE-VEEM)s partially reacted under heating to give crosslinked polymer membranes. The crosslinked membranes showed high CO₂/N₂ selectivity, especially the poly(MEEVE-VEEM) membrane possessing the highest ratio of MEEVE exhibited high CO₂ permeability and high selectivity (P(CO₂) = 120 barrers, P(CO₂)/P(N₂) = 55).