| 聚乙二醇放电介质中洋葱状富勒烯的制备与表面修饰 |
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| 引用本文： | 郭明聪,杨永珍,刘红艳,刘旭光,许并社.聚乙二醇放电介质中洋葱状富勒烯的制备与表面修饰[J].电子显微学报,2009,28(1):52-56. |
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| 作者姓名： | 郭明聪 杨永珍 刘红艳 刘旭光 许并社 |
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| 作者单位： | 1. 太原理工大学,教育部新材料界面与工程重点实验室,山西太原030024;太原理工大学,化学化工学院,山西太原030024
2. 太原理工大学,教育部新材料界面与工程重点实验室,山西太原030024;太原理工大学,材料科学与工程学院,山西太原030024 |
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| 基金项目： | 国家重点基础研究发展规划(973计划)，国家自然科学基金，教育部新世纪优秀人才支持计划，科技部国际科技合作计划 |
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| 摘 要： | 以分子量为600、400和200的聚乙二醇（PEG）为介质电弧放电法制备了洋葱状富勒烯（OLFs）;利用空气氧化法于450℃条件下对产物进行了提纯,并用含氧射频等离子体对纯化后的OLFs进行了表面氧化修饰;用场发射扫描电镜、高分辨透射电镜、X射线衍射和傅立叶变换红外光谱对所得产物进行了表征和分析。结果表明：在PEG200中放电制得的OLFs粒径均匀,石墨化程度较高;空气氧化法能提高OLFs产物的纯度;当氧气含量为20%时,表面氧化修饰效果明显。
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| 关 键 词： | 聚乙二醇 洋葱状富勒烯 制备 提纯 修饰 |
Preparation by arc-discharge in PEG and surface modification of onion-like fullerene |
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| GUO Ming-cong,YANG Yong-zhen,LIU Hong-yan,LIU Xu-guang,XU Bing-she.Preparation by arc-discharge in PEG and surface modification of onion-like fullerene[J].Journal of Chinese Electron Microscopy Society,2009,28(1):52-56. |
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| Authors: | GUO Ming-cong YANG Yong-zhen LIU Hong-yan LIU Xu-guang XU Bing-she |
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| Affiliation: | 1. Key Laboratory of Interface Science and Engineering in Advanced Materials of Taiyuan University of Technology;Ministry of Education;2. College of Chemistry and Chemical Engineering;Taiyuan University of Technology;3. College of Materials Science and Engineering;Taiyuan Shanxi 030024;China |
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| Abstract: | Onion-like fullerenes (OLFs) were synthesized by liquid arc-discharge in polyethylene glycol (PEG) with different molecular weight (600, 400, 200). The as-synthesized products were purified by air oxidation. And then purified OLFs were modified in oxygen-containing radio frequency (RF) plasma. The morphologies and structures of the products were characterized by field emission scanning electron microscopy, high resolution transmission electron microscopy, X-ray diffraction and Fourier transform infrared spe... |
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| Keywords: | polyethylene glycol onion-like fullerenes synthesis purification modification |
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