| 二缩水甘油二甘醇胺封端的聚氨酯型深冷胶黏剂的合成、表征及其性能研究 |
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| 引用本文： | 罗健军,刘强,李镇江,孙鹏,张勇,张林. 二缩水甘油二甘醇胺封端的聚氨酯型深冷胶黏剂的合成、表征及其性能研究[J]. 化学与粘合, 2011, 0(4): 4-8 |
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| 作者姓名： | 罗健军 刘强 李镇江 孙鹏 张勇 张林 |
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| 作者单位： | 中国工程物理研究院激光聚变研究中心;西南科技大学材料与科学工程学院;西南科技大学极端条件物质特性实验室; |
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| 基金项目： | 中物院双百人才基金资助课题(编号:20088074) |
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| 摘 要： | 采用一种新方法来提高环氧封端聚氨酯固化速率和室温以上拉伸剪切强度.先以二甘醇胺和环氧氯丙烷为原料,氢氧化钠溶液作为催化剂合成了二缩水甘油二甘醇胺(DGDGA),并用FT-IR,MS对其结构进行了表征.再以自制的DGDGA对异氰酸酯封端的聚氨酯预聚体进行封端,合成了具有高反应活性的缩水甘油胺型聚氨酯(GAPU),用FT-...
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| 关 键 词： | 二缩水甘油二甘醇胺 缩水甘油胺型封端聚氨酯 缩水甘油氨基甲酸酯 深冷胶黏剂 |
Synthesis,Characterization and Properties of Diglycidyl Diglycolamine Terminated Polyurethane Type Cryogenic Adhesives |
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| LUO Jian-jun,,LIU Qiang,LI Zhen-jiang,SUN Peng,ZHANG Yong , ZHANG Lin. Synthesis,Characterization and Properties of Diglycidyl Diglycolamine Terminated Polyurethane Type Cryogenic Adhesives[J]. Chemistry and Adhesion, 2011, 0(4): 4-8 |
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| Authors: | LUO Jian-jun LIU Qiang LI Zhen-jiang SUN Peng ZHANG Yong ZHANG Lin |
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| Affiliation: | LUO Jian-jun1,3,LIU Qiang3,LI Zhen-jiang1,SUN Peng1,ZHANG Yong3 and ZHANG Lin2(1.Research Center of Laser Fusion,China Academy of Engineering Physics,Mianyang 621900 China,2.College of Materials Science and Engineering,Southwest University of Science and Technology,Mianyang 621010,China,3.Laboratory for Matter Characteristic Research under Extreme Condition,Mianyang,China) |
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| Abstract: | A novel method was developed for the preparation of polyurethane with improved room-temperature curing rate and enhanced tensile shear strength at higher temperatures.Diglycidyl diglycolamine(DGDGA) was prepared through the reaction of epichlorohydrin and ethanolamine with the catalysis of sodium hydroxide aqueous solution.The structure of DGDGA was characterized by FI-IR,MS.DGDGA was used to convert the isocyanate terminated polyurethane prepolymer to glycidylamine terminated polyurethane(GAPU) with high r... |
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| Keywords: | Diglycidyl diglycolamine glycidylamine terminated polyurethane glycidyl carbamate cryogenic adhesives |
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