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Formation of Acicular Monoclinic Zirconia Particles under Hydrothermal Conditions
Authors:Chunting Li  Iwao Yamai  Yashio Murase  Etsuro Kato
Affiliation:Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466, Japan;Government Industrial Research Institute, Nagoya, Hirate-cho, Kita-ku, Nagoya 462, Japan;Aichi Institute of Technology, Vagusa-cho, Toyota-shi 470-03, Japan
Abstract:Acicular monoclinic ZrO2, particles were prepared by hydrothermal treatmentat 250°C using sulfuric acid solutions containing zirconium ions. The formation process and morphology of the ZrO2, particles were investigated. Two types of acicular monoclinic Zr02, particle morphologies were obtained, both elongated in the 〈001〉 direction, and the range of acicular ZrO2, particle sizes changedfrom 0.3 to 1.3 μ m with hydrothermal conditions. Addition of MgSO4, to the starting solution promoted the crystallization of the monoclinic ZrO2, particles.
Keywords:zirconia  formation  particles  hydrothermal processes  and particle
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