| 可控/活性聚合在无机粒子表面接枝研究进展 |
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| 引用本文： | 唐龙祥,刘榛,刘春华,王平华. 可控/活性聚合在无机粒子表面接枝研究进展[J]. 现代塑料加工应用, 2008, 20(6) |
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| 作者姓名： | 唐龙祥 刘榛 刘春华 王平华 |
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| 作者单位： | 合肥工业大学化工学院,安徽,合肥,230009 |
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| 基金项目： | 国家自然科学基金，安徽省高校青年教师科研项目 |
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| 摘 要： | 介绍了一些主要的可控／活性自由基聚合法，包括氮氧调解自由基聚合法（NMRP）、原子转移自由基聚合法（ATRP）、可逆加成断裂链转移聚合法（RAFT）在粒子表面接枝聚合形成无机纳米粒子／聚合物的壳核结构，达到了对粒子改性的目的。并提出了一些目前研究中存在的问题，对可控／活性聚合应用的发展进行了展望。
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| 关 键 词： | 无机纳米粒子 表面接枝 可控活性自由基聚合 氮氧调解自由基聚合 原子转移自由基聚合 可逆加成断裂链转移聚合 |
Development of Surface-Grafting Onto Nano-Particles via Controlled & Living Radical Polymerization |
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| Tang Longxiang,Liu Zhen,Liu Chunhua,Wang Pinghua. Development of Surface-Grafting Onto Nano-Particles via Controlled & Living Radical Polymerization[J]. Modern Plastics Processing and Applications, 2008, 20(6) |
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| Authors: | Tang Longxiang Liu Zhen Liu Chunhua Wang Pinghua |
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| Affiliation: | School of Chemistry;Hefei University of Technology;Hefei;Anhui;230009 |
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| Abstract: | Several controlled/living radical polymerization methods were mainly introduced, including nitroxide-mediated radical polymerization(NMRP),atom transfer radical polymerization(ATRP) and reversible addition-fragmentation chain transfer polymerization (RAFT),in the application of inorganic nano-particles surface-initiated polymerization.The structure of inorganic core/polymer shell was formed,and achieved the aim of surface modification. Moreover,some existed problems in recent years were suggested,and furthe... |
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| Keywords: | inorganic nano-particle surface-grafting controlled/living radical polymerization nitroxide-mediated radical polymerization atom transfer radical polymerization reversible addition-fragmentation chain transfer polymerization |
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