Debye Temperature and Electrical Conduction of Fe2O3-CaO-SiO2 Glasses

The electrical conductivity of iron-containing silica glasses was measured from 80 to 350 K. The conductivity data were analyzed based on the hopping conduction theory. The hopping binding energy (W_p) and disorder energy W_D) were calculated from the activation energy at high and low temperatures. The disorder energy obtained was much lower than reported for FeO-P₂O₅ glasses, but similar to that for vandium-containing glasses.