激光诱导下铈氧化态改变的研究 |
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引用本文: | 刘祖武,童珏. 激光诱导下铈氧化态改变的研究[J]. 中国激光, 1982, 9(9): 567-569 |
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作者姓名: | 刘祖武 童珏 |
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作者单位: | 湘潭大学化学系(刘祖武),湘潭大学化学系(童珏) |
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摘 要: | 在KIO_3-HCl体系中,用氮分子激光作激发光源,研究了铈的价态变化。三价铈的碘酸盐能溶于酸性永溶液,而在激光辐照后,却均匀地、逐渐地生成黄色沉淀。经红外光谱及化学分析证明,此沉淀为四价铈的碘酸盐。
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收稿时间: | 1981-09-28 |
Study on valency change of cerium by laser |
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Abstract: | The valency change cf cerium induced by using nitrogen laser for excitation of KIO3-HCl system has been studied. Cerous iodate is soluble in acidic aqueous solution, but a yellow precipitate is formed homogeneously and gradually after irradiation by laser. It is proved by IR spectrum and chemical analysis that this precipitate is eerie iodate. |
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