The effect of branching and unsaturation upon some properties of polyoxyethylene glycol diesters |
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Authors: | Anthony J O'Lenick Jr Jeffrey K Parkinson |
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Affiliation: | (1) Lambent Technologies Inc., 4437 Park Dr., 30093 GA, Norcross |
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Abstract: | Fatty acid diesters based upon polyoxyethylene glycol (PEG diesters) find applications in many diverse segments of thechemical
industry. PEG diesters contain both a water-soluble and an oil-soluble portion, resulting in a surface-active product. These
surfactants exhibit emulsification properties. A study of PEG diesters was undertaken to determine the effect of the following
variables in the fatty portion of the molecule: (i) number of carbon atoms present, (ii) branching or lack of branching, and
(iii) presence of unsaturation. The objective was to compare titer point, solubilities and emulsification properties of various
PEG-600 based diesters that were synthesized using high-purity linear saturated, Guerbet-branched, and unsaturated acids.
Included in the test was a series of esters based upon meadowfoam oil, a high-molecular-weight unsaturated oil. |
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Keywords: | Ester fatty alcohol Guerbet meadowfoam polyoxyethylene glycol |
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