The surface tensions of indium and cadmium |
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Authors: | D W G White |
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Affiliation: | (1) Department of Energy, Mines, and Resources, ADM (Science and Technology), Ottawa, Ontario, Canada |
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Abstract: | The surface tensions of 99.9999 pct In and Cd have been measured by the sessile drop method. The surface tension/temperature
behavior of liquid indium is nonlinear and within a certainty of 99.5 pct, can be represented by the following quadratic equation:γ
In = 568.0 − 0.04t − 7.08 × 10−5
t
2 ± 5 dyne per cm At its melting point, the surface tension of liquid indium is 560 ± 5 dyne per cm. The slope of the temperature
coefficient of the surface tension of liquid cadmium is strongly positive at the melting point, becomes zero about 100°C above
the melting temperature (at which point the surface tension is a maximum), and is negative at higher temperatures. At the
melting point, the surface tension of cadmium is 590 ± 5 dyne per cm. The surface tension of cadmium is not as readily affected
by nonequilibrium thermal conditions as is the surface tension of zinc. The form of the surface tension/temperature curve
of indium and cadmium together with similar data for Zn, Cu, Pb, and Sn support a theoretical scheme which generalizes liquid
metal surface tension behavior and which, on the basis of calculations, lists liquid metals according to their propensity
for surface ordering. |
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Keywords: | |
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