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γ-CuI晶体的发光衰减时间和对X射线的能量响应
引用本文:李锋锐,顾 牡,何 徽,畅里华,温伟峰,李泽仁,陈 亮,刘金良,欧阳晓平,刘小林,刘 波,黄世明,倪 晨.γ-CuI晶体的发光衰减时间和对X射线的能量响应[J].无机材料学报,2017,32(2):163-168.
作者姓名:李锋锐  顾 牡  何 徽  畅里华  温伟峰  李泽仁  陈 亮  刘金良  欧阳晓平  刘小林  刘 波  黄世明  倪 晨
作者单位:(1. 同济大学 物理科学与工程学院, 上海市特殊人工微结构材料与技术重点实验室, 上海200092; 2. 中国工程物理研究院 流体物理研究所, 绵阳621900; 3. 西北核技术研究所 强脉冲辐射环境模拟与效应国家重点实验室, 西安710024)
基金项目:国家重大科学仪器设备开发专项项目(2011YQ13001902);国家自然科学基金(11475128, 91022002, 11375129);Significant National Special Project of the Ministry of Science and Technology of China for Development of Scientific Instrument and Equipment (2011YQ13001902);National Natural Science Foundation of China (11475128, 91022002, 11375129)
摘    要:采用溶剂蒸发法生长出透明的带隙宽度为2.96 eV的γ-CuI晶体。在紫外光激发下, 该晶体在410、430 nm处分别呈现有近带边发射峰, 另在720 nm附近还出现一个与样品碘缺陷有关的宽发射带。经碘退火后, 样品720 nm发射带被基本抑制, 而在420 nm处出现了一个更强的近带边发射峰。使用扫描相机分别测量了γ-CuI晶体各发射峰(带)的衰减时间谱, 其中近带边发射峰的发光衰减时间常数均在数十皮秒量级, 表明γ-CuI晶体具有极快的时间响应特性; 而720 nm发射带的发光衰减时间常数主要在数十纳秒量级。X射线激发下, γ-CuI晶体具有435 nm近带边发射峰和680 nm发射带, 其近带边发射对X射线能量响应的测量结果表明, 当EX<49.1 keV时, γ-CuI晶体闪烁光快分量对X射线的探测效率相对较高。

关 键 词:γ  -CuI晶体  超快闪烁体  衰减时间  能量响应  
收稿时间:2016-04-18
修稿时间:2016-06-20

Fluorescent Decay Time and Energy Response of γ-CuI Crystal
LI Feng-Rui,GU Mu,HE Hui,CHANG Li-Hua,WEN Wei-Feng,LI Ze-Ren,CHEN Liang,LIU Jin-Liang,OUYANG Xiao-Ping,LIU Xiao-Lin,LIU Bo,HUANG Shi-Ming,NI Chen.Fluorescent Decay Time and Energy Response of γ-CuI Crystal[J].Journal of Inorganic Materials,2017,32(2):163-168.
Authors:LI Feng-Rui  GU Mu  HE Hui  CHANG Li-Hua  WEN Wei-Feng  LI Ze-Ren  CHEN Liang  LIU Jin-Liang  OUYANG Xiao-Ping  LIU Xiao-Lin  LIU Bo  HUANG Shi-Ming  NI Chen
Affiliation:(1. Shanghai Key Laboratory of Special Artificial Microstructure Material & Technology, School of Physics Science and Engineering, Tongji University, Shanghai 200092, China; 2. Institute?of?Fluid?Physics, China Academy of Engineering Physics, Mianyang 621900, China; 3.State Key Laboratory of Intense Pulsed Radiation Simulation and Effect, and Radiation Detection Research Center, Northwest Institute of Nuclear Technology, Xi’an 710024, China)
Abstract:γ-CuI crystal was prepared by using slow solvent evaporation method. The optical transmission spectrum reveals that the crystal is transparent with band gap of 2.96 eV. Two near-band-edge emission peaks are located at 410 nm, 430 nm, and an iodine related defect emission band near 720 nm of the crystal appear under UV excitation. The emission band near 720 nm can be suppressed by iodine annealing, while a new and relative strong near-band-edge emission peaked at 420 nm appears. Decay times of emission peaks and band of γ-CuI crystals were measured by using streak camera. The results show that the decay times of all near-band-edge emission peaks are tens of picosecond, which indicates that γ-CuI crystal is one of the fastest scintillators, but the decay time of the emission band near 720 nm is mainly tens of nanosecond. γ-CuI crystal presents a near-band-edge emission peaked at 435 nm and a broad emission band near 680 nm under X-ray excitation. The energy response of the near- band-edge emission to X-ray shows that the emission has a relatively high response to X-ray when the X-ray energy is less than 49.1 keV.
Keywords:γ  -CuI crystal  ultrafast scintillator  decay time  energy response to X-ray  
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