| Effects of pH value of reaction solution on structure and electrochemical performance of calcium-containing active material of secondary zinc electrodes |
| |
| 引用本文： | 陈华,王建明,郑奕,张鉴清,曹楚南. Effects of pH value of reaction solution on structure and electrochemical performance of calcium-containing active material of secondary zinc electrodes[J]. 中国有色金属学会会刊, 2004, 14(2): 406-411 |
| |
| 作者姓名： | 陈华 王建明 郑奕 张鉴清 曹楚南 |
| |
| 作者单位： | [1]DepartmentofChemistry,ZhejiangUniversity,Hangzhou310027,China [2]State.KeyLaboratoryforMetalsCorrosionandProtection,Shenyang110015,China |
| |
| 摘 要： | The calcium-containing active material of secondary alkaline zinc electrodes was prepared by a chemical coprecipitation method and characterized by scanning electron microscopy(SEM) and X-ray diffractometry(XRD).Their electrochemical performance was tested by the Galvanstatic charge-discharge method. The experimental results show that the sample synthesized at pH: 11. 15 has a typical calcium zincate crystal. The zinc electrode using this sample as active material shows higher discharge capacity, more negative discharge plateau potential and longer cycle lifetime.
|
| 关 键 词： | 氧化锌 锌电极 蓄电池 电化学性能 结构 pH值 SEM XRD |
Effects of pH value of reaction solution on structure and electrochemical performance of calcium-containing active material of secondary zinc electrodes |
| |
| CHEN Hua,WANG Jian-ming,ZHENG Yi,ZHANG Jian-qing. Effects of pH value of reaction solution on structure and electrochemical performance of calcium-containing active material of secondary zinc electrodes[J]. Transactions of Nonferrous Metals Society of China, 2004, 14(2): 406-411 |
| |
| Authors: | CHEN Hua WANG Jian-ming ZHENG Yi ZHANG Jian-qing |
| |
| Affiliation: | CHEN Hua~1,WANG Jian-ming~1,ZHENG Yi~1,ZHANG Jian-qing~ |
| |
| Abstract: | The calcium-containing active material of secondary alkaline zinc electrodes was prepared by a chemical coprecipitation method and characterized by scanning electron microscopy(SEM) and X-ray diffractometry(XRD).Their electrochemical performance was tested by the Galvanstatic charge-discharge method. The experimental results show that the sample synthesized at pH = 11.15 has a typical calcium zincate crystal. The zinc electrode using this sample as active material shows higher discharge capacity, more negative discharge plateau potential and longer cycle lifetime. |
| |
| Keywords: | calcium zincate zinc oxide zinc electrode electrochemical performance |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
