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In-situ formation of layer-like Ag2MoO4 induced by high-temperature oxidation and its effect on the self-lubricating properties of NiCoCrAlYTa/Ag/Mo coatings
Authors:Enkang Hao  Yulong An  Jie Chen  Xiaoqin Zhao  Guoliang Hou  Jianmin Chen  Meizhen Gao  Fengyuan Yan
Abstract:Ag-Mo-O ternary oxide has attracted growing attention because of its potential as a solid lubricant at high temperatures.This work designs and prepares NiCoCrAlYTa/Ag/Mo composite coating,performed using high velocity oxy-fuel(HVOF)spraying technology.The environment temperature plays an important role in the microstructure and phases as well as lubricant properties of NiCoCrAlYTa/Ag/Mo coatings.When the environment temperature is above 600C,the outer diffusion and oxidation of Ag and Mo lead to the formation of Ag2MoO4 on the coating surface.Layer-like Ag2MoO4 could form a continuous lubricant film at 800℃and consequently let the composite coating present the best tribological properties.Meanwhile,a small number of hard particles could play a good bearing role during friction and improve the tribological properties of the composite coating.
Keywords:Microstructure evolution  In-situ formation  Ag2MoO4  Layer-like structure  High-temperature friction
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