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盐产品检验中氯离子含量测量不确定度的评估
引用本文:苑惠杰,赵毅,张仂.盐产品检验中氯离子含量测量不确定度的评估[J].盐业与化工,2014(9):31-35.
作者姓名:苑惠杰  赵毅  张仂
作者单位:中盐工程技术研究院有限公司国家盐产品质量监督检验中心天津市盐化工企业重点实验室,天津300450
基金项目:国家高技术发展计划(863)(2012AA061603); 天津市科技计划项目(12TXGCCX01400)
摘    要:文章依据《化学分析中不确定度的评估指南》,从盐产品中氯离子含量检验的技术规定,识别不确定度的来源,不确定度分量的定量,计算合成标准不确定度,计算扩展不确定度等几个方面,详细阐述了盐产品中氯离子检验过程测量不确定度的评估方法,得出了氯离子检验过程中玻璃量器的体积分量对其测量不确定度贡献最大的结论。

关 键 词:盐产品  氯离子测定  测量不确定度

Evaluation of Uncertainty in the Measurement of Chloride Ion Content in Salt Products
YUAN Hui- jie,ZHAO Yi,ZHANG Le.Evaluation of Uncertainty in the Measurement of Chloride Ion Content in Salt Products[J].Jounral of Salt and Chemical Industry,2014(9):31-35.
Authors:YUAN Hui- jie  ZHAO Yi  ZHANG Le
Affiliation:(Engineering Technology Institute Co., Ltd., of CNSIC, China National Centre of Quality Supervision and Testing of Salt Products, Tianjin Enterprise Key Laboratory of Salt Chemical Industry, Tianjin 300450, China)
Abstract:Based on the Guidance on Evaluating the Uncertainty in Chemical Analysis, the evaluation of uncertainty in the measurement of chloride ion content in salt products are discussed in detail for the aspects of technical requirements for measurement of chloride ion, identifying the sources of uncertainty, quantifying the components of uncertainty, calculating the total standard uncertainty and expanded uncertainty, etc. The conclusion was that the volume component of working glass containers made the greatest contributions to the uncertainty in the measurement of chloride ion content.
Keywords:salt products  measurement of chloride ion  uncertainty
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