| 4,6-二异戊氧基-1,3-二磺酰二甲基胺的一锅合成 |
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| 引用本文： | 王文革,张德春,袁杏. 4,6-二异戊氧基-1,3-二磺酰二甲基胺的一锅合成[J]. 天津化工, 2011, 25(5): 27-28,31. DOI: 10.3969/j.issn.1008-1267.2011.05.009 |
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| 作者姓名： | 王文革 张德春 袁杏 |
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| 作者单位： | 湖南工学院材料与化学工程系,湖南 衡阳,421002 |
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| 基金项目： | 衡阳市科学技术局科技计划项目(2010KS42); 湖南工学院科学研究项目(HY10009,HY09016) |
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| 摘 要： | 以4,6-二异戊氧基-1,3-二磺酰氯和N,N-二甲基羟基胺为原料,三乙胺作催化剂,二氯甲烷作溶剂,采取一锅煮反应的方法合成了1种N,N-二取代磺酰胺类化合物,并通过IR和单晶x-射线衍射对其组成结构进行了表征。4,6-二异戊氧基-1,3-二磺酰二甲基胺属于单斜晶系,P2（1）/c空间群,晶胞参数a=14.866（3）A,b=15.903（3）A,c=11.567（2）A,α=90°,β=112.88（3）°,γ=90°,V=2519.5（9）A3,Z=4,R=0.089 1,wR=0.264 8。
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| 关 键 词： | 磺酰胺 一锅法 中间体 有机合成 |
One-Pot Synthesis and characterization of 4,6-Bis-(3-methy1 lbutyloxy)-benzene-1,3-disulfonic acid bis-dimethylamide |
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| WANG Wen-Ge,ZHANG De-Chun,YUAN Xing. One-Pot Synthesis and characterization of 4,6-Bis-(3-methy1 lbutyloxy)-benzene-1,3-disulfonic acid bis-dimethylamide[J]. Tianjin Chemical Industry, 2011, 25(5): 27-28,31. DOI: 10.3969/j.issn.1008-1267.2011.05.009 |
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| Authors: | WANG Wen-Ge ZHANG De-Chun YUAN Xing |
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| Affiliation: | WANG Wen-Ge,ZHANG De-Chun,YUAN Xing(Department of materials & Chemical Engineering,Hunan Institute of Technology,Hengyang Hunan 421002,China) |
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| Abstract: | 4,6-Bis-(3-methylbutyloxy)-benzene-1,3-disulfonic acid bis-dimethylamide was synthesized in one pot by using 4,6-Bis-(3-methylbutyloxy)-benzene-1,3-disulfonyl dichlorides and N,N-dimethyl hydroxyl amine as the starting materials,triethylamine as the catalyst,and dichloromethane as the solvent.The purified products was characterized by IR and X-Ray crystallography.Compound 2 belongs to monoclinic system with space group P2(1)/c and a = 14.866(3) A,b = 15.903(3)A,c=11.567(2)A,α=90°,β=112.88(3)°,γ=90°,V=2519.5(9)A3,Z=4,R=0.089 1,wR=0.264 8. |
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| Keywords: | sulfonamide one-pot intermediate organic synthesis |
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