| DATB TATB和其中间体的新合成法 |
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| 引用本文： | 魏运洋. DATB TATB和其中间体的新合成法[J]. 兵工学报, 1992, 13(2): 79-81 |
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| 作者姓名： | 魏运洋 |
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| 作者单位： | 华东工学院 |
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| 摘 要： | 间硝基苯甲酸(la)和3,5-二硝基苯甲酸(1b)在超酸介质中与叠氮化钠作用,分别生成间硝基苯胺(2a)和3,5-二硝基苯胺(2b)。利用2a和2b的进一步反应,得到1,3-二氨基-2,4,6-三硝基苯(DATB)和1,3,5-三氨基-2,4,6-三硝基苯(TATB)。这是一种合成耐热炸药DATB和TATB的新途径。
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| 关 键 词： | 硝基化合物 炸药 施密特反应 |
A NEW METHOD FOR THE PREPARATION OF DATB,TATB AND THEIR INTERMEDIATES |
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| Wei Yunyang. A NEW METHOD FOR THE PREPARATION OF DATB,TATB AND THEIR INTERMEDIATES[J]. Acta Armamentarii, 1992, 13(2): 79-81 |
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| Authors: | Wei Yunyang |
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| Affiliation: | East China Institute of Technology |
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| Abstract: | Treating m-nitrobenzoic acid (la) and 3, 5-dinitrobenzoic acid (1b) with sodium azide in super-acid medium gave m-nitroaniline (2a) and 3, 5-dinitroaniline (2b), respectively. 1, 3-diarnino-2, 4, 6-trinitrobenzene (DATB) and 1, 3, 5-triamino-2, 4, 6-trinitrobenzene (TATB) were then obtained via further reactions of the intermediates, 2a and 2b. This represents a new route for the preparation of heat-resistant explosives, DATB and TATB. |
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| Keywords: | nitro compounds heat-resistant explosives Schmidt reaction nitration |
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