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壳聚糖双胍盐酸盐对羊毛织物抗菌性能的影响
引用本文:赵雪,乔真真,何瑾馨,展义臻.壳聚糖双胍盐酸盐对羊毛织物抗菌性能的影响[J].毛纺科技,2009,37(10).
作者姓名:赵雪  乔真真  何瑾馨  展义臻
作者单位:1. 东华大学化学化工与生物工程学院,上海,201620
2. 三元控股集团有限公司,浙江,杭州,311221
摘    要:利用壳聚糖和双氰胺成功地合成了一种壳聚糖双胍盐酸盐(CGH),应用红外光谱确认了聚合物的结构.采用整理剂CGH,交联剂柠檬酸和催化剂次亚磷酸钠按照轧-烘-焙工艺整理羊毛织物,使其获得良好的抗菌性能.运用扫描电子显微镜SEM和傅里叶变换红外光谱图对抗菌剂CGH,交联剂柠檬酸与羊毛之间的交联机理进行了探讨.结果表明,整理后的羊毛织物具有良好的抗菌性和耐洗涤性能.

关 键 词:壳聚糖双胍盐酸盐  羊毛  交联  柠檬酸  抗菌

Effects of chitosan biguanidine hydrochloride antimicrobial property on wool fabric
ZHAO Xue,QIAO ZHEN-zhen,HE JIN-xin,ZHAN Yi-zhen.Effects of chitosan biguanidine hydrochloride antimicrobial property on wool fabric[J].Wool Textile Journal,2009,37(10).
Authors:ZHAO Xue  QIAO ZHEN-zhen  HE JIN-xin  ZHAN Yi-zhen
Affiliation:1.College of Chemistry & Chemical Engineering;Donghua University;Shanghai 201620;China;2.Saintyear Holding Group Company;Hangzhou 311221;China
Abstract:Chitosan biguanidine hydrochloride(CGH) has been synthesized by the guanidinylation reaction of chitosan with dicyandiamide.The structures of CGH were characterized by FT-IR.In this paper,it used CGH,crosslinking agent citric acid and catalyst sodium hypophosphite to endue with the properties of antimicrobial to wool fabric through pad-dry-cure treatment.Scanning electron microscopy(SEM) and Fourier Transform Infrared Spectroscopy(FTIR) were employed to study the re-action mechanism during crosslinking of t...
Keywords:chitosan biguanidine hydrochloride  wool  crosslinking  citric acid  antimicrobial  
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