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Oxidative cyanide-free cyanation on arylboronic acid derivatives using aryl/heteroaryl thiocyanate using novel IL-PdCl4 catalyst under mild condition |
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| Authors: | Beena K Vaghasiya Shailesh P Satasia Rahul P Thummar Ronak D Kamani Jemin R Avalani Nirav H Sapariya |
| Affiliation: | 1. Department of Chemistry, Sardar Patel University, Vallabh Vidyanagar, Gujarat, India;2. Shree A. N. Patel P. G. Institute of Science and Research, Anand, Gujarat, India;3. Natubhai V. Patel College of Pure and Applied Sciences, Vallabh Vidyanagar, Gujarat, India |
| Abstract: | An efficient and simple method is reported for the cyanation on arylboronic acid using various simple/indole thiocyanates using a new IL-PdCl4 catalyst. The cascade process involves a coupling reaction without any additive to give a wide range of cyanide derivatives. Cyanation on various arylboronic acids underwent smoothly affording the corresponding arylnitriles in good to high yields. |
| Keywords: | Thiocyanation IL-PdCl4 FE-SEM arylboronic acid indoline derivatives |