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CuCrZr合金表面等离子喷涂Cr3C2-NiCr及NiAl/Cr3C2-NiCr涂层的结合性能
引用本文:陈健,刘雪飘,梁欢,崔庭,方锴.CuCrZr合金表面等离子喷涂Cr3C2-NiCr及NiAl/Cr3C2-NiCr涂层的结合性能[J].焊接学报,2012,33(5):13-16.
作者姓名:陈健  刘雪飘  梁欢  崔庭  方锴
作者单位:1. 江苏科技大学先进焊接技术省级重点实验室,镇江,212003
2. 上海三一科技有限公司,昆山,215301
3. 上海三一重机有限公司,昆山,215301
基金项目:江苏高校优势学科建设工程资助项目
摘    要:在CuCrZr合金表面等离子喷涂Cr3C2-NiCr涂层、NiAl/Cr3C2-NiCr复合涂层.测试涂层与基体间的结合强度及涂层的热震性能,结合SEM,EDS和XRD等分析涂层物相变化,探讨涂层的结合机理.结果表明,涂层的结合强度均较高;Ni-Al发生放热反应,生成Al4Ni3,Al3Ni2,AlNi3,剩余的铝与铜反应生成Cu3Al2,CuAl2,CuAl,局部区域形成微冶金结合;二种涂层均以机械锚合为主,在参数适合且基体相同的情况下,涂层结合强度取决于涂层材料的力学性能;相同试验条件下,NiAl/Cr3C2-NiCr复合涂层的热震性能优于Cr3C2-NiCr涂层.

关 键 词:等离子喷涂  Cr3C2-NiCr涂层  结合强度  CuCrZr合金
收稿时间:2011/3/26 0:00:00

Bonding properties of plasma sprayed Cr3C2-NiCr and NiAl/Cr3C2-NiCr coatings on CuCrZr alloy surface
CHEN Jian,LIU Xuepiao,LIANG Huan,CUI Ting and FANG Kai.Bonding properties of plasma sprayed Cr3C2-NiCr and NiAl/Cr3C2-NiCr coatings on CuCrZr alloy surface[J].Transactions of The China Welding Institution,2012,33(5):13-16.
Authors:CHEN Jian  LIU Xuepiao  LIANG Huan  CUI Ting and FANG Kai
Affiliation:1(1.Provincial Lab of Advanced Welding Technology,Jiangsu University of Science and Technology,Zhenjiang 212003,China;2.Shanghai Sany Science & Technology Co.,Ltd.,Kunshan 215301,China;3.Shanghai Sany Heavy Machinery Co.,Ltd,Kunshan 215301,China)
Abstract:The Cr3C2-NiCr,NiAl/Cr3C2-NiCr coatings were prepared by plasma spraying on the CuCrZr alloy.The bonding strength between the coating and the substrate and the thermal shock resistance were tested.The change of the phases and the coating bonding mechanism were investigated by means of SEM,EDS,XRD.The results show all coatings have good bonding strength.During the process of spraying the NiAl coating,an exothermic reaction generates between Ni and Al,and three kinds of intermetallics(Al4Ni3,Al3Ni2,AlNi3) are formed.The remaining Al can react with Cu substrate to form Cu3Al2,CuAl2 and CuAl,hence,the micro-metallurgical bond exists in some micro-zones.However,the bond type is mainly mechanical bond for all coatings.The bonding strength depends on the mechanical properties of the coating material,under the conditions of the same substrate and appropriate parameters.The thermal shock resistance of NiAl/Cr3C2-NiCr coating is better than that of Cr3C2-NiCr coating.
Keywords:plasma spraying  Cr3C2-NiCr coating  bonding strength  CuCrZr alloy
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