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Sn-Zn-Ga-xPr钎料组织与性能
引用本文:李阳,薛松柏,杨晶秋,叶焕,陈澄,顾立勇,顾文华. Sn-Zn-Ga-xPr钎料组织与性能[J]. 焊接学报, 2012, 33(5): 33-36
作者姓名:李阳  薛松柏  杨晶秋  叶焕  陈澄  顾立勇  顾文华
作者单位:1. 南京航空航天大学材料科学与技术学院,南京,210016
2. 哈尔滨焊接研究所,哈尔滨,150080
3. 常熟市华银焊料有限公司,常熟,215513
基金项目:2010年度“江苏省企业研究生工作站”资助项目
摘    要:研究了添加合金元素Ga及稀土元素Pr对Sn-Zn钎料组织与性能的影响.适量添加镨,可以提高钎料的润湿性能;但当镨含量超过0.12%(质量分数)时,镨会在钎料表面形成氧化渣,恶化钎料的润湿性能.镨的添加可以改善焊点的力学性能,抗剪强度在镨含量为0.08%时增加至最大.镨加入后细化了钎料基体中的富锌相,当镨含量不超过0.08%时,界面层平整且厚度变化不大,但若稀土添加过量,则界面层会明显增厚.镨在Sn9Zn0.5Ga钎料中的最佳添加量为0.08%左右.

关 键 词:SnZn钎料  润湿性  力学性能  显微组织
收稿时间:2011-11-30

Microstructure and properties of Sn-Zn-Ga-xPr lead-free solder
LI Yang,XUE Songbai,YANG Jingqiu,YE Huan,CHEN Cheng,GU Liyong and GU Wenhua. Microstructure and properties of Sn-Zn-Ga-xPr lead-free solder[J]. Transactions of The China Welding Institution, 2012, 33(5): 33-36
Authors:LI Yang  XUE Songbai  YANG Jingqiu  YE Huan  CHEN Cheng  GU Liyong  GU Wenhua
Affiliation:1.College of Materials Science and Technology,Nanjing University of Aeronautics and Astronautics,Nanjing 210016,China;2.Harbin Welding Institute,Harbin 150080,China;3.Changshu Huayin Filler Metals Co.,Ltd,Changshu 215513,China)
Abstract:Effects of rare earth element Pr additions on the microstructure and properties of Sn-Zn-Ga solder were studied in this paper.The wettability of solder was significantly improved by 0.08%Pr addition.However,the wettability of solder would deteriorate when the Pr addition exceeds 0.12% due to the oxidization of Pr element at the liquid surface.Moreover,the mechanical property of solder joint was improved by Pr addition and the maximum shear strength was obtained when 0.08% Pr was added.The Zn-rich phase in the solder matrix was refined by Pr but the thickness of interface layer showed no obvious difference when Pr was less than 0.08%.When excessive Pr was added,the interface layer thickness of the joint increased significantly,so that the optimal content of Pr in the Sn9Zn0.5Ga solder is about 0.08%.
Keywords:Sn-Zn fill metal  wettability  mechanical properties  microstructure
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