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铝基体上碳纳米管原位均匀合成及其复合材料的性能
引用本文:李海鹏,范佳薇,康建立,赵乃勤,王雪霞,李宝娥. 铝基体上碳纳米管原位均匀合成及其复合材料的性能[J]. 中国有色金属学会会刊, 2014, 24(7): 2331-2336. DOI: 10.1016/S1003-6326(14)63353-7
作者姓名:李海鹏  范佳薇  康建立  赵乃勤  王雪霞  李宝娥
作者单位:天津大学材料科学与工程学院;河北工业大学材料科学与工程学院;天津工业大学材料科学与工程学院;
基金项目:Projects(51071107,51001080,51201056)supported by the National Natural Science Foundation of China;Project(2010CB934703)supported by the National Basic Research Program of China;Project(13211027)supported by Science and Technology Plan Project of Hebei Province,China;Project(2011008)supported by Outstanding Youth Science and Technology Innovation Fund of Hebei University of Technology,China
摘    要:采用负载于铝粉上的镍催化剂,成功地在650℃通过化学气相沉积法在钳基体中原位合成碳纳米管。结构农征表明,所合成的碳纳米管具有较高的石墨化程度和平直的石墨壳层。通过该方法实现铝粉中碳纳米管的弥散分布,其分散效果优于传统机械混合方法。利用所合成的碳纳米管/铝原位复合粉末,采用粉末冶金工艺制备碳纳米管/铝基复合材料。性能测试表明,制备的复合材料的力学性能和尺寸稳定性得到显著提高,其原因在于铝基体中碳纳米管的均匀分散和碳纳米管-铝基体之间良好的界面结合。

关 键 词:铝基复合材料  碳纳米管  化学气相沉积  原位合成
收稿时间:2013-10-17

In-situ homogeneous synthesis of carbon nanotubes on aluminum matrix and properties of their composites
Hai-peng LI,Jia-wei FAN,Jian-li KANG,Nai-qin ZHAO,Xue-xia WANG,Bao-e LI. In-situ homogeneous synthesis of carbon nanotubes on aluminum matrix and properties of their composites[J]. Transactions of Nonferrous Metals Society of China, 2014, 24(7): 2331-2336. DOI: 10.1016/S1003-6326(14)63353-7
Authors:Hai-peng LI  Jia-wei FAN  Jian-li KANG  Nai-qin ZHAO  Xue-xia WANG  Bao-e LI
Affiliation:Hai-peng LI, Jia-wei FAN, Jian-li KANG, Nai-qin ZHAO, Xue-xia WANG, Bao-e LI( 1. School of Materials Science and Engineering, Tianjin University, Tianjin 300072, China; 2. School of Materials Science and Engineering, Hebei University of Technology, Tianjin 300130, China; 3. School of Materials Science and Engineering, Tianjin Polytechnic University, Tianjin 300387, China)
Abstract:Using nickel catalyst supported on aluminum powders, carbon nanotubes (CNTs) were successfully synthesized in aluminum powders by in-situ chemical vapor deposition at 650 ℃. Structural characterization revealed that the as-grown CNTs possessed higher graphitization degree and straight graphite shell. By this approach, more homogeneous dispersion of CNTs in aluminum powders was achieved compared with the traditional mechanical mixture methods. Using the in-situ synthesized CNTs/Al composite powders and powder metallurgy process, CNTs/Al bulk composites were prepared. Performance testing showed that the mechanical properties and dimensional stability of the composites were improved obviously, which was attributed to the superior dispersion of CNTs in aluminum matrix and the strong interfacial bonding between CNTs and matrix.
Keywords:aluminum matrix composites  carbon nanotubes  chemical vapor deposition  in-situ synthesis
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