| 直接顶空进样-气质联用法测定塑胶地垫中有毒有害挥发性有机物 |
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| 引用本文： | 李彬,余淑媛,张伟亚,徐维嘉,刘丽,王宏菊,张珠福,刘志红,吴景武,邹春海,任聪.直接顶空进样-气质联用法测定塑胶地垫中有毒有害挥发性有机物[J].塑料科技,2010,38(4). |
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| 作者姓名： | 李彬 余淑媛 张伟亚 徐维嘉 刘丽 王宏菊 张珠福 刘志红 吴景武 邹春海 任聪 |
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| 作者单位： | 深圳出入境检验检疫局,广东,深圳,518045 |
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| 摘 要： | 采用直接顶空进样法快速测定塑胶地垫中的有毒有害挥发性有机物的含量,利用气相色谱-质谱总离子流进行定性分析,选择离子流并用外标法进行定量分析,对顶空进样的平衡时间、平衡温度及色谱的分离条件分别做了优化,并进行了线性范围、回收率、精密度等试验。结果表明:9种目标化合物的线性范围为10~1000mg/L;相关系数为0.9960~0.9997;方法的检测低限为12.4~61.2ng/g;平均回收率为88.6%~112%;相对标准偏差小于8.6%。所建方法适用于塑胶地垫中苯、1-丁醇、甲苯等有毒有害挥发性有机物的测定。
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| 关 键 词： | 直接顶空进样 塑胶地垫 有机挥发物 气相色谱-质谱法 |
Determination of Harmful Volatile Organic Compounds in Plastic Floor Cushion by Direct Headspace Injection-Gas Chromatography-Mass Spectrometry |
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| Li Bin,Yu Shuyuan,Zhang Weiya,Xu Weijia,Liu Li,Wang Hongiu,Zhang Zhufu,Liu Zhihong,Wu Jingwu,Zou Chunhai,Ren Cong.Determination of Harmful Volatile Organic Compounds in Plastic Floor Cushion by Direct Headspace Injection-Gas Chromatography-Mass Spectrometry[J].Plastics Science and Technology,2010,38(4). |
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| Authors: | Li Bin Yu Shuyuan Zhang Weiya Xu Weijia Liu Li Wang Hongiu Zhang Zhufu Liu Zhihong Wu Jingwu Zou Chunhai Ren Cong |
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| Affiliation: | Li Bin,Yu Shuyuan,Zhang Weiya,Xu Weijia,Liu Li,Wang Hongju,Zhang Zhufu,Liu Zhihong,Wu Jingwu,Zou Chunhai,Ren CongShenzhen Entry-Exit Inspection , Quarantine Bureau,Shenzhen 518045,China |
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| Abstract: | A rapid direct headspace injection method was employed for the determination of harmful volatile organic compounds. The qualitative and quantitative analysis were performed by total ion chromatogram and selected ion chromatogram respectively with GC-MS for the nine target compounds. The balance time and balance temperature of headspace injection and seperation conditions of chromatography were optimized. The tests of linearity range, recovery rate and precision were performed. The results show that the line... |
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| Keywords: | Direct headspace injection Plastic floor cushion Volatile organic compound Gas chromatography-mass spectrometry |
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