1-hexene isomerization over bimetallic M-Mo-ZSM-5 (M: Fe,Co, Ni) zeolite catalysts: Effects of transition metals addition on the catalytic performance |
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| Affiliation: | 1. Department of Catalysis and Chemical Reaction Engineering, National Institute of Chemistry, Hajdrihova 19, Ljubljana 1001, Slovenia;2. PetroSA Synthetic Fuels Innovation Centre, South African Institute for Advanced Materials Chemistry, University of the Western Cape, Cape Town, Private Bag X17, Bellville, 7535, South Africa;1. School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, China;2. National Institute of Advanced Industrial Science and Technology (AIST), 16-1 Onogawa, Tsukuba, Ibaraki 305-8569, Japan;1. Key Laboratory of Biofuels, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, PR China;2. College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042, PR China;1. College of Chemical Engineering, China University of Petroleum, Qingdao 266555, China;2. State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Qingdao 266555, China |
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| Abstract: | The aim of this study is to investigate the promotional effect of Fe–Mo, Co–Mo, and Ni–Mo bimetallic additives on the activity and stability of H-ZSM-5 zeolite for isomerization of 1-hexene. The catalysts were synthesized by wet-impregnation method and characterized by XRD, FTIR, BET, ICP-AES, HRSEM-EDS, HRTEM, H2-TPR, NH3-TPD, and pyridine-DRIFT analysis. The isomerization of 1-hexene was carried out in a micro-scale system under the conditions: T = 250 °C, P = 4.0 MPa, FR = 0.1 ml/min, WHSV = 1 h−1. The conversion of 1-hexene over the 4 g bed of catalyst was in the range of 95–97% after 74 h time-on-stream with cis-3-hexene and cis-2-hexene as the principal products. It was shown that the appearance of the new strong Lewis acid sites, decreases the ratio of Brönsted/Lewis acid sites. Increase of the weak Lewis acid sites in the 2.5 wt%Ni2.5 wt%Mo-ZSM-5 catalyst facilitated the isomerization of 1-hexene and showed higher C6 olefin selectivity (48.4 mol%), research octane number (99.7), and bromine number (148.3) than other studied catalysts. |
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| Keywords: | H-ZSM-5 Metal additives Isomerization 1-hexene Brönsted/Lewis acid sites |
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