Synthesis, Surface, Thermodynamic Properties of Some Biodegradable Vanillin-Modified Polyoxyethylene Surfactants |
| |
Authors: | Galal Hosni Sayed Ferial Mohamed Ghuiba Mahmoud Ibrahim Abdou Emad Abdel Aatty Badr Salah Mahmoud Tawfik Nabel Abdel Moneem Negm |
| |
Affiliation: | 1. Chemistry Department, Faculty of Science, Ain Shams University, Cairo, Egypt 2. Egyptian Petroleum Research Institute, Nasr City, Cairo, Egypt
|
| |
Abstract: | Four water-soluble non-ionic ethoxylated surfactants based on vanillin were synthesized (VE15, VE20, VE40, and VE60). The chemical structures of these surfactants were confirmed using FT-IR and 1H-NMR spectra. The molecular weights of the compounds were determined using viscosity measurements and gel permeation chromatography. Surface tension as a function of the concentration of the surfactant in aqueous solution was measured at 25, 40 and 55?°C. From these measurements, the critical micelle concentration (CMC), effectiveness (??cmc), efficiency (pC20), maximum surface (??max) excess and minimum surface area (A min), were calculated. The surface activity measurements showed their high tendency towards adsorption and micellization and their good surface tension reduction, and low interfacial tension. The emulsion stability measurements showed the applicability of these surfactants as emulsifying agents. The thermodynamic parameters of micellization (??G mic, ??H mic, ??S mic) and adsorption (??G ads, ??G ads, ?S ads) showed their tendency towards adsorption at the interfaces and also micellization in the bulk of their solutions. The biodegradability of the prepared surfactants was tested in river water using die-away method and showed their readily biodegradation in the open environment. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|