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Sintering and dielectric properties of 0.88Al2O3-0.12TiO2 microwave ceramics by glass addition
Authors:Wen-Cheng Tzou  Sang-Li ChangCheng-Fu Yang  Ying-Chung Chen
Affiliation:a Department of Electrical Engineering, Fortune Institute of Technology, Chishan, Kaohsiung, Taiwan 842, ROC
b Department of Electrical Engineering, National Sun Yat-Sen University, Kaohsiung, Taiwan 804, ROC
c Department of Electronic Engineering, Chinese Air Force Academy, P.O. Box 90277-4, Kangshan, Kaohsiung, Taiwan 820, ROC
Abstract:The microwave characteristics and the microstructures of 0.88Al2O3-0.12TiO2 with various amounts of MgO-CaO-SiO2-Al2O3 (MCAS) glass sintered at different temperatures have been investigated. The sintering temperature can be lowered to 1300 °C by the addition of MCAS glass. The densities, dielectric constants (εr) and quality values (Q×f) of the MCAS-added 0.88Al2O3-0.12TiO2 ceramics decrease with the increase of MCAS glass content. The temperature coefficients of the resonant frequency (τf) are shifted to more negative values as the MCAS content or the sintering temperatures increase. The change of the crystalline phases of Al2TiO5 phase and rutile-TiO2 phase has profound effects on the microwave dielectric properties of the MCAS-added Al2O3-TiO2 ceramics. As sintered at 1250 °C, 0.88Al2O3-0.12TiO2 ceramics with 2 wt.% MCAS glass addition exists a εr value of 8.63, a Q×f value of 9578 and a τf value of +5 ppm/°C.
Keywords:A  Ceramics  A  Glasses  C  X-ray diffraction  D  Dielectric properties
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