| 含锡催化剂在Baeyer-Villiger氧化反应中的应用进展 |
| |
| 引用本文： | 黄靓,李静霞,戴维林,曹勇,范康年.含锡催化剂在Baeyer-Villiger氧化反应中的应用进展[J].石油化工,2007,36(2):200-204. |
| |
| 作者姓名： | 黄靓 李静霞 戴维林 曹勇 范康年 |
| |
| 作者单位： | 复旦大学化学,系上海市分子催化与创新材料重点实验室,上海200433 |
| |
| 基金项目： | 国家自然科学基金;上海市科委资助项目 |
| |
| 摘 要： | 综述了近年来含锡催化剂在Baeyer-Villiger反应(酮转化为相应的酯或内酯的反应)中的应用研究进展,分别介绍了Sn-β沸石、Sn-MCM-41、水滑石负载锡、坡缕石负载锡等非均相催化剂及锡的全氟化辛烷磺酰胺配合物、苯胺和苯甲醇取代的有机锡配合物等均相催化剂。由于非均相催化剂能回收重复利用,着重介绍了各种非均相催化剂的优缺点及催化作用机理。其中,Sn-β沸石由于具有较多的小孔,有利于Sn的嵌入,从而有效提高了反应的转化率,而Sn-MCM-41、水滑石负载锡、坡缕石负载锡等催化剂虽合成方法简单,但其活性均低于Sn-β沸石催化剂。
|
| 关 键 词： | Baeyer-Villiger氧化反应 含锡催化剂 酮 酯 内酯 |
| 文章编号： | 1000-8144(2006)02-0200-05 |
| 修稿时间： | 2006年9月20日 |
Progress in Application of Tin-Containing Catalysts to Baeyer-Villiger Oxidation |
| |
| Huang Jing,Li Jingxia,Dai Weilin,Cao Yong,Fan Kangnian.Progress in Application of Tin-Containing Catalysts to Baeyer-Villiger Oxidation[J].Petrochemical Technology,2007,36(2):200-204. |
| |
| Authors: | Huang Jing Li Jingxia Dai Weilin Cao Yong Fan Kangnian |
| |
| Abstract: | Recent development in research of tin-containing catalysts used in Baeyer-Villiger oxidation was reviewed. The heterogeneous and homogeneous catalysts, namely Sn-β zeolite, Sn-MCM-41, Sn-hydrotalcite, Sn-palygorskite, Sn-perfluorooctanesulfonyl amide complex, aniline-Sn and benzyl alcohol-Sn, were introduced. Catalytic mechanisms of some catalysts for the oxidation were discussed. The heterogeneous catalysts can be reused. Because Sn can be easily introduced into micropores on Sn-β zeolite support, activity of catalyst in the reaction is high. Activity of other heterogeneous catalysts are lower than that of Sn-β zeolite, although their preparation processes are much more simple. |
| |
| Keywords: | Baeyer-Villiger oxidation reaction tin-containing catalyst ketone ester lactone |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
