Chloromethane Conversion to Higher Hydrocarbons over Zeolites and SAPOs |
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Authors: | Dazhi Zhang Yingxu wei Lei Xu Aiping Du Fuxiang Chang Bao-lian Su Zhongmin Liu |
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Affiliation: | (1) Natural Gas Utilization and Applied Catalysis Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, P.O. Box 110, Dalian, 116023, P.R. China;(2) Laboratoire de Chimie des Matériaux Inorganiques (CMI), The University of Namur (FUNDP), B-5000 Namur, Belgium;(3) Graduate school of the Chinese Academy of Sciences, Beijing, 100039, P.R. China |
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Abstract: | Chloromethane transformations were carried out over zeolites and SAPOs and the conversion and product distribution differed
from the porous structure and acidity of the catalysts. Chloromethane was mainly transferred to higher hydrocarbons in gasoline
range over most of zeolite catalysts, while SAPOs molecular sieves, SAPO-34 and SAPO-5, showed high selectivity for light
olefins production, such as ethylene, propylene and butenes. TG analysis was used to study the coke formation during the transformation
and the acid difference of the catalysts was evidenced by Temperature programmed desorption of ammonia. HZSM-5, with high
activity and less coke formation, was proved to be a potential catalyst for hydrocarbons production from chloromethane conversion.
It is of particular interest that SAPO-34 gave an excellent performance in light olefins production from chloromethane transformation,
which may be attributed to the shape selectivity and medium strong acidity of SAPO-34. |
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Keywords: | Chloromethane transformation ZSM-5 SAPO-34 higher hydrocarbons light olefins |
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