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国产CPVC树脂和进口树脂性能的对比分析
引用本文:王艳芳,徐保良,滕谋勇,仪修杰,孙巧珍. 国产CPVC树脂和进口树脂性能的对比分析[J]. 塑料工业, 2011, 39(Z1)
作者姓名:王艳芳  徐保良  滕谋勇  仪修杰  孙巧珍
作者单位:聊城大学材料科学与工程学院,山东,聊城,252059
摘    要:选取国内外同类型的典型的CPVC树脂进行结构表征及性能测试,探讨树脂存在的差距.利用扫描电子显微镜/X射线能谱仪(SEM/EDS)、同步热分析仪(DSC/TG)对两种树脂进行全面的表征和比较.结果表明:国产树脂与进口树脂存在一定的差距,国产CPVC粒子皮膜连续且厚实;加工温度范围窄,塑炼易变色,热稳定性差,需要从提高PVC质量、改进氯化工艺以及加强PVC,CPVC表征分析等方面着手,加快研发速度,逐步改观我国CPVC技术落后,产品质量差的现状.

关 键 词:氯化聚氯乙烯  微观形貌  表面氯含量  凝胶化度  热稳定性

Comparison Analysis on the Property of Domestic and Imported CPVC Resin
WANG Yan-fang,XU Bao-liang,TENG Mou-yong,YI Xiu-jie,SUN Qiao-zhen. Comparison Analysis on the Property of Domestic and Imported CPVC Resin[J]. China Plastics Industry, 2011, 39(Z1)
Authors:WANG Yan-fang  XU Bao-liang  TENG Mou-yong  YI Xiu-jie  SUN Qiao-zhen
Affiliation:WANG Yan-fang1,XU Bao-liang1,TENG Mou-yong1,YI Xiu-jie1,SUN Qiao-zhen1(Department of Material Science and Engineering,Liaocheng University,Shandong 252059,China)
Abstract:The difference between the domestic and imported CPVC was investigated through SEM,EDS,DSC and TG.The two CPVC resins structure were characterized and compared.The results showed: There was discrepancy between them.The skin film of domestic resin was continuous and thick which had a narrow range of processing temperature,easy heat discoloration and poor thermal stability.By improving PVC quality,chlorination process,strengthening characterization analysis of PVC and CPVC,speeding the research and developmen...
Keywords:CPVC  Microstructure  Surface Chloride Content  Degree of Gelatin  Thermal Stability  
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