A novel infinite 1D covalent chain of end-to-end thiocyanato bridged heptacoordinated cadmium(II)Schiff base: π…π interaction and weak C–H…S hydrogen bonded supramolecule |
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| Authors: | Sk Hafijur Rahaman Rajarshi Ghosh Golam Mostafa Barindra Kumar Ghosh |
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| Affiliation: | aDepartment of Chemistry, The University of Burdwan, Burdwan 713 104, India;bDepartment of Physics, Jadavpur University, Kolkata 700 032, India |
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| Abstract: | A new Schiff base, N,N′-(bis(pyridin-2-yl)formylidene)ethane-1,2-diamine (bpfd) is prepared and used to synthesize a novel end-to-end thiocyanato bridged infinite 1D polymeric heptacoordinated cadmium(II) chain Cd(bpfd)(μ1,3-NCS)(NCS)]n (1) which forms a 3D supramolecule through weak C–H…S hydrogen bonding and π…π interaction. |
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| Keywords: | Cadmium(II) Thiocyanate Schiff base 1D chain C– H… S hydrogen bonding |
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