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羟基氧化镍的研究进展
引用本文:何汉兵,周科朝,李志友. 羟基氧化镍的研究进展[J]. 电源技术, 2008, 32(3): 197-200
作者姓名:何汉兵  周科朝  李志友
作者单位:中南大学,粉末冶金国家重点实验室,湖南,长沙,410083;中南大学,粉末冶金国家重点实验室,湖南,长沙,410083;中南大学,粉末冶金国家重点实验室,湖南,长沙,410083
摘    要:羟基氧化镍作为锌镍电池和MH-Ni电池的正极活性物质已经逐步成为电池材料领域一个新的研究热点。综述了锌镍电池和MH-Ni电池的工作原理及羟基氧化镍的制备、结构、电性能;分析了羟基氧化镍的放电比容量及Ni(OH)2/NiOOH电极的可逆电极电势;围绕高放电比容量、自放电率低、高密度羟基氧化镍的发展前景,建议了今后的研究方向。

关 键 词:羟基氧化镍  锌镍电池  MH-Ni电池  放电比容量  可逆电极电势
文章编号:1002-087X(2008)03-0197-04
修稿时间:2007-09-25

Research progress of nickel oxyhydroxides
HE Han-bing,ZHOU Ke-chao,LI Zhi-you. Research progress of nickel oxyhydroxides[J]. Chinese Journal of Power Sources, 2008, 32(3): 197-200
Authors:HE Han-bing  ZHOU Ke-chao  LI Zhi-you
Abstract:In recent years, as a cathode active material of Zn-Ni battery and Ni-MH battery, nickel oxyhydroxide has gradually become a new research issue in the area of the battery materials. The mechanism of Zn-Ni battery and Ni-MH battery, and the preparations, the crystal structures and the electrochemical properties of nickel oxyhydroxides were reviewed, and the discharging specific capacity of nickel oxyhydroxide and reversible electrode potential of Ni(OH)2/NiOOH electrode were also analyzed. At last, according to the perspectives of high discharging specific capacity, low self-discharging rate and high density NiOOH, the research directions in the future were suggested.
Keywords:nickel oxyhydroxide  Zn-Ni battery  Ni-MH battery  discharging specific capacity  reversible electrode potential
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