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中温煤焦油重馏分加氢裂化的工艺条件优化
引用本文:李斌,李冬,李稳宏,崔楼伟,雷雨辰,王军策,刘存菊,李宏.中温煤焦油重馏分加氢裂化的工艺条件优化[J].化工进展,2012,31(5):1023-1027.
作者姓名:李斌  李冬  李稳宏  崔楼伟  雷雨辰  王军策  刘存菊  李宏
作者单位:西北大学化工学院,陕西 西安 710069
基金项目:2010陕西省“13115”科技创新工程,陕西省自然科学基金,西安市科技局创新支撑计划,陕西省教育厅2010年产业化培育项目,陕西省教育厅自然科学基金(2010JK874)项目
摘    要:在小型单管固定床加氢装置上,研究中温煤焦油重馏分加氢裂化工艺过程各因素对裂化效果的影响。通过单因素和响应面法对加氢裂化率与工艺条件进行分析、拟合及优化求解得中温煤焦油重馏分加氢裂化的优化条件为:反应压力13.4 MPa,裂化温度682 K,液体体积空速0.30 h-1,氢油体积比1895∶1,煤焦油加氢裂化率为77%~78%。

关 键 词:煤焦油  重馏分加氢  加氢裂化  响应面优化

Optimization for the hydrocracking process of the heavy fraction of medium temperature coal tar
LI Bin,LI Dong,LI Wenhong,CUI Louwei,LEI Yuchen,WANG Junce,LIU Cunju,LI Hong.Optimization for the hydrocracking process of the heavy fraction of medium temperature coal tar[J].Chemical Industry and Engineering Progress,2012,31(5):1023-1027.
Authors:LI Bin  LI Dong  LI Wenhong  CUI Louwei  LEI Yuchen  WANG Junce  LIU Cunju  LI Hong
Affiliation:School of Chemical Engineering,Northwest University,Xi’an 710069,Shaanxi,China
Abstract:Analysis and optimization of hydrocracking process conditions for the heavy fraction of medium temperature coal tar in a fixed-bed hydrogenation unit was investigated using single-factor tests and response surface methodology. The optimized process condition was found as:reaction pressure of 13.4 MPa,reaction temperature of 682 K,hydrogen to oil volume ratio of 1895?1 and liquid hourly space velocity of 0.30 h?1,under which the conversion rate of the heavy fraction of coal tar hydrogenation was 77%-78%.
Keywords:medium temperature coal tar  heavy fractions hydrogenation  hydrocracking  responsesurface optimization
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