High-Pressure Viscosity and Density Measurements for the Asymmetric Binary System cis-Decalin +2,2,4,4,6,8,8-Heptamethylnonane |
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Authors: | M. Barrouhou C. K. Zebérg-Mikkelsen A. Baylaucq C. Boned |
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Affiliation: | (1) Laboratoire des Fluides Complexes, UMR CNRS, Faculté des Sciences et Techniques, n[Université de Pau, Avenue de l'Université, BP 1155, 64013 Pau Cedex, France |
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Abstract: | Measurements of the viscosity and density of seven binary mixtures composed of cis-decahydronaphthalene (cis-decalin)+2,2,4,4,6,8,8-heptamethylnonane along with the pure compounds have been performed in the temperature range 293.15 to 353.15 K and at pressures up to 100 MPa. The viscosity was measured with a falling-body viscometer, except at 0.1 MPa where a classical capillary viscometer (Ubbelohde) was used. The experimental uncertainty for the measured viscosities is less than 2% at high pressures. The density was measured up to 60 MPa with a resonance densimeter and extrapolated with a Tait-type relationship up to 100 MPa. The uncertainty for the reported densities is less than 1 kg m–3. The measured data have been used in an evaluation of the simple mixing laws of Grunberg and Nissan and of Katti and Chaudhri, which require only the density and viscosity of the pure compounds. This evaluation showed that these mixing laws can accurately represent the viscosity of this asymmetric binary system within an average absolute deviation of 1%. |
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Keywords: | 2,2,4,4,6,8,8-heptamethylnonane cis-decalin density high pressure hydrocarbon mixtures viscosity |
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