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Primary nucleation of lithium carbonate
Authors:Yuzhu SUN  Xingfu SONG  Jin WANG  Yan LUO  Jianguo YU
Affiliation:(1) State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai, 200237, China
Abstract:A set of laser apparatus was used to explore the induction period and the primary nucleation of lithium carbonate. Results show that the induction period increases with the decrease of supersaturation, temperature and stirring speed. Through the classical theory of primary nucleation, many important properties involved in primary nucleation under different conditions were obtained quantitatively, including the interfacial tension between solid and liquid, contact angle, critical nucleus size, critical nuleation free energy etc.
Keywords:lithium carbonate  primary nucleation  reactive crystallization  induction period
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