| Ti-C-Al-Fe_2O_3反应体系的热力学及形成产物的分析 |
| |
| 引用本文： | 焦玉凤,陈学琴,金宝士.Ti-C-Al-Fe_2O_3反应体系的热力学及形成产物的分析[J].佳木斯工学院学报,2010(3):408-411. |
| |
| 作者姓名： | 焦玉凤 陈学琴 金宝士 |
| |
| 作者单位： | [1]佳木斯大学材料科学与工程学院,黑龙江佳木斯154007 [2]佳木斯技师学院焊接教研室,黑龙江佳木斯154002 |
| |
| 基金项目： | 黑龙江省佳木斯大学科研项目（12007-08）;黑龙江省教育厅耐磨材料研发中心项目（E080002）. |
| |
| 摘 要： | 针对Ti-C-Al-Fe2O3体系进行了热力学计算,并结合DSC及XRD分析,为研究该体系反应合成TiC,Al2O3提供了理论依据.计算结果表明：该体系在发生SHS反应时,可以生成TiC,Al2O3,Fe2Ti,TiAl3,Fe3C和Al4C3等产物,但TiC,Al2O3的热力学稳定性要远远大于Fe2Ti,TiAl3,Fe3C和Al4C3等相,因此,在1600℃的钢液引燃的SHS反应过程中,只能生成TiC,Al2O3两种产物.通过XRD分析也证明了在反应产物中只有TiC,Al2O3两种物质形成.
|
| 关 键 词： | SHS 热力学计算 DSC分析 XRD分析 |
Analysis on the Thermodynamics and Formation of Ti-C-Al- Fe2O3 System Reaction |
| |
| Affiliation: | JIAO Yu -feng , CHEN Xue - qing , JIN Bao - shi ( 1. College of Materials Science and Engineering, Jiamusi University, Jiamusi 154007, China; 2. Department of Welding, Jiamusi Technician College, Jiamusi 154007, China) |
| |
| Abstract: | Several compounds such as TiC, Al2O3, Fe2Ti, TiAl3, Fe3C and Al4C3 may formed in the Ti -C -Al -Fe2O3 system, but because the thermodynamic stability of TiC and A1203 is much higher than that of Fe2Ti, TiAl3, Fe3C and Al4C3 etc. according to the thermodynamic calculations, only stable ceramic phases of TiC and Al2O3 can exist in the liquid steel at 1600℃ stably. The results of XRD analysis proved that only TiC and Al2O3 particulates were found in the reaction product. |
| |
| Keywords: | self - propagation high - temperature synthesis thermodynamic calculation DSC analysis XRD analysis |
| 本文献已被 维普 等数据库收录！ |
|
