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PA6/PPO共混物的非等温结晶动力学
引用本文:朱小磊;吴盾;刘春林;王琛;张刚.PA6/PPO共混物的非等温结晶动力学[J].中国塑料,2012,26(1):29-34.
作者姓名:朱小磊;吴盾;刘春林;王琛;张刚
作者单位:常州大学 常州大学 常州大学
摘    要:采用差示扫描量热法研究了聚酰胺6/聚苯醚(PA6/PPO)共混物的非等温结晶动力学。通过Jeziorny法、Mo法分别对非等温结晶过程进行处理。结果表明,PPO对PA6结晶起促进作用,而马来酸酐接枝聚苯醚(PPO-g-MAH)、氢化聚苯乙烯-丁二烯-苯乙烯嵌段共聚物(SEBS)和SEBS-g-MAH对PA6的结晶起阻碍作用;随着冷却速率的增大,共混物的结晶度下降,半结晶时间减小;Jeziorny和Mo法都适合分析PPO/PA6的非等温结晶过程。

关 键 词:聚苯醚  聚酰胺6  共混物  非等温结晶  动力学  
收稿时间:2011-9-16

Non-isothermal Crystallization Kinetics of PA6/PPO Blends
ZHU Xiaolei,WU Dun,LIU Chunlin,WANG Chen,ZHANG Gang.Non-isothermal Crystallization Kinetics of PA6/PPO Blends[J].China Plastics,2012,26(1):29-34.
Authors:ZHU Xiaolei  WU Dun  LIU Chunlin  WANG Chen  ZHANG Gang
Affiliation:(School of Materials Science and Engineering,Changzhou University,Changzhou 213164,China)
Abstract:The non-isothermal crystallization behavior of PA6/PPO blends was studied with differential scanning calorimetry.The methods of Jeziorny and Mo were used to analyze the non-isothermal crystallization kinetics of the blends.Results demonstrated that the crystallization of PA6 could be accelerated by PPO,however,depressed by PPO-g-MAH,SEBS-g-MAH and SEBS.Both Jeziorny and Mo methods were suitable for the analysis of non-isothermal crystallization of PA6/PPO blends.
Keywords:polyphenylene ether  polyamide 6  blend  non-isothermal crystallization  kinetics
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