| 离子液体在原子转移自由基聚合反应中的研究进展 |
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| 引用本文： | 杨美珠,张力,石光,刘石军,叶鑫.离子液体在原子转移自由基聚合反应中的研究进展[J].广东化工,2007,34(10):59-63. |
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| 作者姓名： | 杨美珠 张力 石光 刘石军 叶鑫 |
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| 作者单位： | 华南师范大学,化学与环境学院,广东,广州,510006;华南师范大学,化学与环境学院,广东,广州,510006;华南师范大学,化学与环境学院,广东,广州,510006;华南师范大学,化学与环境学院,广东,广州,510006;华南师范大学,化学与环境学院,广东,广州,510006 |
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| 摘 要： | 作为一种新型环境友好的"绿色溶剂",室温离子液体已逐步被人们认识和接受。近年来人们将之应用在聚合反应中的研究越来越多,特别是近年发展起来的原子转移自由基活性聚合反应中,使用离子液体不仅可以增大聚合速率和分子量,而且有助于催化剂与聚合物的分离。本文根据近几年的文献资料,阐述了原子转移自由基聚合机理以及离子液体在其中的应用。
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| 关 键 词： | 离子液体 原子转移自由基 反向原子转移自由基 |
| 修稿时间： | 2007-05-04 |
Research Progress of Ionic Liquids in Atom Transfer Radical Polymerization |
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| Yang Meizhu,Zhang Li,Shi Guang,Liu Shijun,Ye Xin.Research Progress of Ionic Liquids in Atom Transfer Radical Polymerization[J].Guangdong Chemical Industry,2007,34(10):59-63. |
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| Authors: | Yang Meizhu Zhang Li Shi Guang Liu Shijun Ye Xin |
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| Affiliation: | Department of Chemistry and Environment, South China Normal University, Guangzhou 510006, China |
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| Abstract: | As a new type of solvent which is friendly to environment,room temperature ionic liquid is known and accepted gradually by the people.More and more researches of polymerization in ionic liquids system were carried out in recent years.Especially for atom transfer radical polymerization developed recently,ionic liquid system not only increases the speed of polymerization and the molecular weight,but the separation of catalyzer from polymers becomes easy.Based on the latest publications in the literature,this paper illustrated the mechanism of free radical polymerization and the application of ionic liquids in atom transfer polymerization. |
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| Keywords: | ionic liquid atom transfer radical polymerization reverse atom transfer radical polymerization |
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