| 4-氨基-6-特丁基-3-甲硫基-1,2,4-三嗪-5(4H)-酮硫酸盐的合成工艺及活性研究 |
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| 引用本文： | 陈邦,范代娣,刘源发,孙晓红. 4-氨基-6-特丁基-3-甲硫基-1,2,4-三嗪-5(4H)-酮硫酸盐的合成工艺及活性研究[J]. 化学工程, 2009, 37(10) |
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| 作者姓名： | 陈邦 范代娣 刘源发 孙晓红 |
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| 作者单位： | 西北大学化工学院,陕西,西安,710069;西北大学合成与天然功能分子化学教育部重点实验室,化学系,陕西,西安,710069;西北大学化工学院,陕西,西安,710069;西北大学合成与天然功能分子化学教育部重点实验室,化学系,陕西,西安,710069;西北大学化工学院,陕西,西安,710069;西北大学化学研究所,陕西,西安,710069 |
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| 摘 要： | 为了寻找新型的除草剂,以浓硫酸和三嗪为起始原料,采用选择性S-甲基化的方法在酸性条件下,对4-氨基-6-特丁基-3-甲硫基-1,2,4-三嗪-5(4H)-酮硫酸盐在合成过程中的各个反应参数进行优化,确定了最优反应条件。通过氢谱(1HNMR),红外光谱(IR),元素分析和熔点测定,对所合成的产物进行结构分析。采用离体含毒介质法对合成产物进行杀菌毒力活性的测定,表明对植物病害菌有良好的抑制和杀灭作用,所得数据为新型除草剂的研究提供科学依据。
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| 关 键 词： | 4-氨基-6-特丁基-3-甲硫基-1 2 4-三嗪-5(4H)-酮硫酸盐 合成工艺 结构分析 活性研究 |
Synthesis process and biological activity of 4-amino-6-tert-butyl-3-methylthio-1,2,4-triazin-5(4H)-one sulfate |
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| CHEN Bang,FAN Dai-di,LIU Yuan-fa,SUN Xiao-hong. Synthesis process and biological activity of 4-amino-6-tert-butyl-3-methylthio-1,2,4-triazin-5(4H)-one sulfate[J]. Chemical Engineering, 2009, 37(10) |
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| Authors: | CHEN Bang FAN Dai-di LIU Yuan-fa SUN Xiao-hong |
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| Abstract: | To search for new pesticide,the parameters in the synthesis process of 4-amino-6-tert-butyl-3-methylthio-1,2,4-triazin-5(4H)-one sulfate were optimized by adopting selective S-methylation and introducing sulphate and triaza as initial ingredients.The structure of this component was analyzed and its indoor virulence was researched by manipulating hydrogen chromatography(1HNMR),infrared spectra(IR),analyzing element and measuring melting temperature.The indoor virulence of inhibit-kill bacteria experiment indicates that this component possesses extinctive ability to inhibit the cultivation of bacteria.So the data of the research supply the valuable scientific references for the field of pesticide. |
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| Keywords: | 4-amino-6-tert-butyl-3-methylthio-1,2,4-triazin-5(4H)-one sulfate synthesis process structure analysis activity research |
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