Relative Cation-Anion Diffusion in Alkyltriethylammonium-Based Ionic Liquids |
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Authors: | Danuta Kruk,Elż bieta Masiewicz,Karol Koł odziejski,Roksana Markiewicz,Stefan Jurga |
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Affiliation: | 1.Department of Physics and Biophysics, University of Warmia & Mazury in Olsztyn, Oczapowskiego 4, 10-719 Olsztyn, Poland; (E.M.); (K.K.);2.NanoBioMedical Centre, Adam Mickiewicz University, Wszechnicy Piastowskiej 3, 61-614 Poznan, Poland; (R.M.); (S.J.) |
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Abstract: | 19F Nuclear Magnetic Resonance spin-lattice relaxation experiments have been performed for a series of ionic liquids including the same anion, bis(trifluoromethanesulfonyl)imide, and cations with alkyl chains of different lengths: triethylhexylammonium, triethyloctylammonium, decyltriethylammonium, dodecyltriethylammonium, decyltriethylammonium, and hexadecyltriethylammonium. The experiments have been carried out in a frequency range of 10 kHz to 10 MHz versus temperature. A thorough analysis of the relaxation data has led to the determination of the cation–anion as a relative translation diffusion coefficient. The diffusion coefficients have been compared with the corresponding cation–cation and anion–anion diffusion coefficients, revealing a correlation in the relative translation movement of the anion and the triethylhexylammonium, triethyloctylammonium, decyltriethylammonium, and dodecyltriethylammonium cations, whereas the relative translation diffusion between the anion and the cations with the longer alkyl chains, decyltriethylammonium and hexadecyltriethylammonium, remains rather uncorrelated (correlated to a much lesser extent). |
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Keywords: | ionic liquids relaxation dynamics diffusion nuclear magnetic resonance correlation effects |
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