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Er3+掺杂TiO2空心球的制备及其光催化性能研究
引用本文:曲晓飞,刘鲁英,李雪钦,杜芳林.Er3+掺杂TiO2空心球的制备及其光催化性能研究[J].无机材料学报,2015,30(2):183-188.
作者姓名:曲晓飞  刘鲁英  李雪钦  杜芳林
作者单位:(青岛科技大学 材料科学与工程学院, 青岛266042)
基金项目:国家自然科学基金重点项目(51272115);山东省优秀中青年科学家科研奖励基金(BS2013CL025);山东省自然科学基金(ZR2012EMM001)~~
摘    要:以钛酸四丁酯、氧化铒、硝酸等为原料, 采用碳球模板法制备了TiO2: Er3+空心球材料, 利用扫描电子显微镜(SEM)、透射电子显微镜(TEM)、X射线衍射(XRD)等测试方法, 对样品的结构和形貌进行了表征。并利用紫外-可见(UV-Vis)分光光度计考察了TiO2: Er3+空心球材料在催化染料罗丹明B、亚甲基蓝、茜素红、甲基橙的脱色降解过程中的应用性能。系统研究了Er3+掺杂浓度、不同离子型染料和染料水溶液的pH等因素对催化降解效率的影响。实验结果表明: 经600℃煅烧3 h制备的TiO2: Er3+为锐钛矿晶型, 空心球结构, 尺寸均匀, 粒径约为120 nm, 比表面积约为60.5 m2/g; Er3+掺杂量为0.5mol%的样品对甲基橙染料的催化降解效率最高; 对四种不同离子型染料, 茜素红的催化降解效果显著, 在紫外光照射下, 催化效率较未掺杂Er3+的TiO2提高了约30%。

关 键 词:Er3+掺杂  TiO2  空心球  光催化降解  
收稿时间:2014-05-19
修稿时间:2014-08-26

Preparation of TiO2: Er3+ Hollow Spheres and Its Photocatalytic Properties
QU Xiao-Fei;LIU Lu-Ying;LI Xue-Qin;DU Fang-Lin.Preparation of TiO2: Er3+ Hollow Spheres and Its Photocatalytic Properties[J].Journal of Inorganic Materials,2015,30(2):183-188.
Authors:QU Xiao-Fei;LIU Lu-Ying;LI Xue-Qin;DU Fang-Lin
Affiliation:(College of Materials Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042, China)
Abstract:Using tetrabutyl titanate, erbium oxide and nitric acid as raw materials, TiO2: Er3+ hollow spheres were prepared with carbon spheres as template. The structures and morphologies of the obtained samples were characterized by scanning electron microscopy (SEM), transmission electron microscope (TEM), and X-ray diffraction (XRD). The photocatalytic activities were studied by degradation of organic pollutants (rhodamine B, methylene blue, alizarin red, methyl orange) using UV-Vis spectrophotometer. The factors, such as Er3+ dopant concentration, pH of the dye solution, on the photocatalytic activities were discussed. The results showed that uniform and well crystallized TiO2: Er3+ hollow spheres in an anatase phase, with diameter of 120 nm could be obtained via carbon-template method followed by a heat treatment at 600℃ for 3 h. The specific surface area of the TiO2: Er3+ hollow spheres was about 60.5 m2/g. When the Er3+ dopant concentration was 0.5 mol% of Ti4+ ions in TiO2, the photocatalytic activity of catalyst on the methyl orange was better than the other samples. Among the four different organic pollutants, the photocatalytic activity on the alizarin red was best. TiO2: 0.5mol%Er3+ showed the better photocatalytic properties than the undoped TiO2. The photodegradation efficiency of alizarin red with TiO2: 0.5mol%Er3+ was 30% higher than that with the undoped TiO2 under UV light irradiation.
Keywords:Er3+ doping  TiO2  hollow spheres  photocatalytic degradation  
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