A STUDY ON ESTERIFIED COPOLYMER OF MALEIC ANHYDRIDE AND VINYL ACETATE AS POUR-POINT DEPRESSANT FOR DIESELS |
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Authors: | Liao Ke-Jian Zhai Yuchun |
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Affiliation: | a Department of Applied Chemistry, Fushun Petroleum Institute, Liaoning, P.R.C.b Institute of Material and Metallurgy, North-East University, Liaoning, P.R.C. |
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Abstract: | The synthesis and using conditions of esterified copolymer of maleic anhydride and vinyl acetate (ESMVA) as pour-point depressant for diesel fuels were investigated. ESMVA was produced by using Maleic a hydride, vinyl acetate and 1-tetradecyl alcohol as raw materials, benzene and toluene as solvents, azobisisobutyronitrile (AIBN) as initiator, p-toluene sulfuric-acid as catalyst, at 138°C, for 6h. It was used in 10 diesel samples. PP(Pour-Point) of 0# diesel from Jinzhou Refinery was lowered by 14∼23°Cand CFPP(Cold Filter Plugging Point) 2∼4°C, PP of 0# diesel from Yanshan Refinery 16∼30°C and CFPP 2°C. Depression mechanism of ESMVA was discussed. |
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Keywords: | Maleic anhydride Vinyl acetate Synthesis Pour-Point Depressant Diesel Fuel Esterification |
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