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电去离子技术再生化学镀镍老化液的研究
引用本文:邢明秀,刘贵昌,王昊,王立达. 电去离子技术再生化学镀镍老化液的研究[J]. 电镀与环保, 2012, 32(3): 46-48. DOI: 10.3969/j.issn.1000-4742.2012.03.016
作者姓名:邢明秀  刘贵昌  王昊  王立达
作者单位:1.大连理工大学化工学院,辽宁大连,116024;2.大连理工大学化工学院,辽宁大连,116024;3.大连理工大学化工学院,辽宁大连,116024;4.大连理工大学化工学院,辽宁大连,116024
摘    要:采用电去离子技术去除化学镀镍老化液中残余的Ca2+,考察了不同工艺条件对Ca2+的去除率的影响.结果表明:随着电流的增加,Ca2+的去除率增大;凝胶型阳树脂比大孔型阳树脂更有利于对Ca2+的去除.在实验所用电流条件下,溶液的DH值在酸性范围内,同时对EDI膜堆进行了改造,增加极室保护室,避免了膜堆结垢.

关 键 词:电去离子  离子交换树脂  Ca2+  化学镀镍废液

An Investigation into Regeneration of Spent Electroless Nickel Plating Bath by Electrodeionization
XING Ming-xiu , LIU Gui-chang , WANG Hao , WANG Li-da. An Investigation into Regeneration of Spent Electroless Nickel Plating Bath by Electrodeionization[J]. Electroplating & Pollution Control, 2012, 32(3): 46-48. DOI: 10.3969/j.issn.1000-4742.2012.03.016
Authors:XING Ming-xiu    LIU Gui-chang    WANG Hao    WANG Li-da
Affiliation:(School of Chemical Engineering,Dalian University of Technology,Dalian 116024,China)
Abstract:Electrodeionization was used to remove the residual Ca2+ in spent electroless nickel plating bath,and the effects of different technological conditions on the removal rate of Ca2+ was investigated.The results show that with the increasing of the film stack current,the removal rate of Ca2+ increases and gel-type ion exchange resin is more beneficial to remove Ca2+ than macro-reticular type ion exchange resin.Under the experimental current conditions,pH values are within acidic range.Furthermore,the modification of the EDI membrane reactor avoids the membrane stack scaling.
Keywords:electrodeionization  ion exchange resin  calcium ion  spent electroless nickel plating bath
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