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Preparation and Thermoelectric Properties of Zr_(1-x)Ti_xNiSn_(0.975)Sb_(0.025) Half-Heusler Alloys
Authors:Cui Yu  Yun Zhang  Tiejun Zhu  Guangyu Jiang  Ji Xu  Bo Zhao    Xinbing Zhao State Key Laboratory of Silicon Materials
Affiliation:Cui Yu,Yun Zhang,Tiejun Zhu,Guangyu Jiang,Ji Xu,Bo Zhao , Xinbing Zhao State Key Laboratory of Silicon Materials,Department of Materials Science , Engineering,Zhejiang University,Hangzhou 310027,China
Abstract:Zr1-xTixNiSn0.975Sb0.025 (x=0, 0.15, 0.25, 0.5) half-Heusler thermoelectric materials have been prepared by levitation melt, melt spinning and hot pressing. X-ray diffraction analysis and scanning electron microscopy observation showed that nearly single phase half-Heusler compounds were obtained for the levitation-melted ingots. The effects of Ti substitution and grain refinement by melt spinning have been studied. It is found that both the Ti substitution on the Zr site and the grain refinement can reduce...
Keywords:Thermoelectric materials  Thermoelectric properties  Half-Heusler alloys  Levitation melting  Grain refinement  
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