| 铜酞菁聚甲基丙烯酸甲酯的合成与表征 |
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| 引用本文： | 邓建成,殷焕顺,周燕,张海良. 铜酞菁聚甲基丙烯酸甲酯的合成与表征[J]. 精细化工中间体, 2005, 35(4): 39-41 |
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| 作者姓名： | 邓建成 殷焕顺 周燕 张海良 |
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| 作者单位： | 湘潭大学,化学学院,湖南,湘潭,411105;湘潭大学,化学学院,湖南,湘潭,411105;湘潭大学,化学学院,湖南,湘潭,411105;湘潭大学,化学学院,湖南,湘潭,411105 |
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| 摘 要： | 以氯甲基化铜酞菁为引发剂,过渡金属卤化物和配位剂(Cu2Cl2/2,2`-联吡啶)为催化体系,进行甲基丙烯酸甲酯原子转移自由基聚合反应,合成出了铜酞菁聚甲基丙烯酸甲酯,并对其进行了结构表征。
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| 关 键 词： | 铜酞菁 氯甲基化 原子转移自由基聚合 |
| 文章编号： | 1009-9212(2005)04-0039-03 |
| 收稿时间： | 2005-03-02 |
| 修稿时间： | 2005-03-02 |
Synthesis and Characterization of Copper Phthalocyanine-end-capped poly [Methyl methacrylate] |
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| DENG Jian-cheng,YIN Huan-shun,ZHOU Yan,ZHANG Hai-liang. Synthesis and Characterization of Copper Phthalocyanine-end-capped poly [Methyl methacrylate][J]. Fine Chemical Intermediates, 2005, 35(4): 39-41 |
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| Authors: | DENG Jian-cheng YIN Huan-shun ZHOU Yan ZHANG Hai-liang |
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| Abstract: | A novel copper phthalocyanine-end-capped poly[methyl methacrylate] was synthesized by atom transfer radical polymerization (ATRP) using chloromethylate copper phthalocyanine as an initiator and CuBr/2,2-bipydrine as a catalyst. The structure and molecular weight of the copper phthalocyanine PMMA was confirmed by GPC, IR and UV/VIS spectrum. |
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| Keywords: | Copper phthalocyanine-end-capped poly [Methyl methacrylate] chloromethylation atom transfer radical polymerization |
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