Viscometric behaviour of hydrophobically modified poly(sodium acrylate) |
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Authors: | K. T. Wang I. Iliopoulos R. Audebert |
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Affiliation: | (1) Laboratoire de Physico-Chimie Macromoléculaire, Université Pierre et Marie Curie, U.A. CNRS n278, E.S.P.C.I., 10, rue Vauquelin, F-75231 Paris Cedex 05, France |
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Abstract: | Summary Hydrophobically associating poly(acrylic acid) was obtained by reaction of a small amount of octadecylamine on the carboxyl groups of the polymer. In pure water, this modified polymer exhibits a very high thickening power. By increasing the ionic strength of the aqueous solution a strong viscosity increase can be obtained instead of the decrease classically observed with polyelectrolytes. For instance, in 1% NaCl the modified poly(sodium acrylate) is of several orders of magnitude more viscous than the precursor polymer. |
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